Mesoporous molecular sieves as advanced supports for olefin metathesis catalysts
作者： H. Balcar , J. Čejka
DOI: 10.1016/J.CCR.2013.07.026
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摘要: Abstract Mesoporous molecular silicas and aluminas based materials are excellent model supports for modification with catalytically active species various organic reactions. They offer well-ordered structures, although of amorphous type, high BET areas, large mesopore volumes, particularly the flexibility in pore size adjustment. For application metathesis, two principal ways incorporation sites were investigated. The first one represents inorganic oxides (W, Mo, Re) while second is on immobilization organometallic complexes (Mo, Ru, W). This review discusses preparation properties both types heterogeneous catalysts relates them to activities, selectivities, time-on-stream stabilities different metathesis Particular attention devoted role mesoporous (textural properties, sizes connectivities) as well catalyst recycling, real performance without any leaching species, tolerance toward functional groups substrates under study.
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sci-hub.se 参考文章(140)
Tushar Shinde, Naděžda Žilková, Vladimíra Hanková, Hynek Balcar, Hoveyda-Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves—The influence of pore size on the catalyst activity Catalysis Today. ,vol. 179, pp. 123- 129 ,(2012) , 10.1016/J.CATTOD.2011.06.012
Carlos Márquez‐Alvarez, Naděžda Žilková, Joaquín Pérez‐Pariente, Jiří Čejka, Synthesis, Characterization and Catalytic Applications of Organized Mesoporous Aluminas Catalysis Reviews. ,vol. 50, pp. 222- 286 ,(2008) , 10.1080/01614940701804042
Takashi Oikawa, Tooru Ookoshi, Tsunehiro Tanaka, Takashi Yamamoto, Makoto Onaka, A new heterogeneous olefin metathesis catalyst composed of rhenium oxide and mesoporous alumina Microporous and Mesoporous Materials. ,vol. 74, pp. 93- 103 ,(2004) , 10.1016/J.MICROMESO.2004.04.026
Kazuhiko Amakawa, Sabine Wrabetz, Jutta Kröhnert, Genka Tzolova-Müller, Robert Schlögl, Annette Trunschke, In situ generation of active sites in olefin metathesis. Journal of the American Chemical Society. ,vol. 134, pp. 11462- 11473 ,(2012) , 10.1021/JA3011989
Mahmood Ahmed, Anthony G.M. Barrett, D.Christopher Braddock, Susan M. Cramp, Panayiotis A. Procopiou, A recyclable ‘boomerang’ polymer-supported ruthenium catalyst for olefin metathesis Tetrahedron Letters. ,vol. 40, pp. 8657- 8662 ,(1999) , 10.1016/S0040-4039(99)01833-X
Mitsunori Yada, Hiroaki Hiyoshi, Kaoru Ohe, Masato Machida, Tsuyoshi Kijima, Synthesis of Aluminum-Based Surfactant Mesophases Morphologically Controlled through a Layer to Hexagonal Transition Inorganic Chemistry. ,vol. 36, pp. 5565- 5569 ,(1997) , 10.1021/IC970292D
Jaehong Lim, Su Seong Lee, Jackie Y. Ying, Mesoporous silica-supported catalysts for metathesis: application to a circulating flow reactor Chemical Communications. ,vol. 46, pp. 806- 808 ,(2010) , 10.1039/B917986K
Takehiko Ono, Masakazu Anpo, Yutaka Kubokawa, Catalytic activity and structure of molybdenum trioxide highly dispersed on silica The Journal of Physical Chemistry. ,vol. 90, pp. 4780- 4784 ,(1986) , 10.1021/J100411A014
Jörg P. Thielemann, Christian Hess, Structure of silica-supported molybdenum oxide studied by in situ spectroscopy under reactive and non-reactive conditions Journal of Catalysis. ,vol. 288, pp. 124- 126 ,(2012) , 10.1016/J.JCAT.2012.01.007
Bogdan Marciniec, Szymon Rogalski, Marek J. Potrzebowski, Cezary Pietraszuk, Ruthenium Carbene Siloxide Complexes Immobilized on Silica: Synthesis and Catalytic Activity in Olefin Metathesis Chemcatchem. ,vol. 3, pp. 904- 910 ,(2011) , 10.1002/CCTC.201000376