The reactivity of C( 1 D) with oxygen bearing molecules NO and O 2 at low temperature

作者: Dianailys Nuñez-Reyes , Kevin M. Hickson

DOI: 10.1016/J.CPLETT.2017.09.028

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摘要: Abstract The gas-phase reactions, C( 1 D) + NO and D) + O 2 have been studied over the 50–296 K range using a Laval nozzle reactor. D) atoms were produced by CBr 4 photolysis. A tracer technique was employed to follow kinetics adding H or CH flow. H-atoms D) + H /CH reactions detected laser-induced fluorescence. Rate constants for reaction show little variation with temperature, whereas rate increase rapidly below 100 K. Numerical simulations performed evaluate influence of secondary reactions.

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