Influence of chromium interaction with native and impurity defects on optical and luminescence properties of ZnSe:Cr crystals

作者: I. Radevici , K. Sushkevich , G. Colibaba , V. Sirkeli , H. Huhtinen

DOI: 10.1063/1.4837596

关键词:

摘要: Luminescent properties of the chromium doped zinc selenide crystals with various concentrations doping impurity in 0.03–0.30 at. % range within temperature interval from 6 K to 300 K were studied. Chromium was performed technological processes: during growth by chemical vapor transport method; melt; thermal diffusion Bi + Cr melt or gas. Possibility chromium-bound excitons formation shown, as well participation emission bands IR spectral region. A mechanism interaction uncontrolled background impurities and structural defects proposed based on experimental data. An assumption about resonant energy transfer between double charged ions complexes vacancy made.

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