Detoxification of methyl-parathion pesticide in aqueous solutions by electrochemical oxidation

作者: D. Arapoglou , A. Vlyssides , C. Israilides , A. Zorpas , P. Karlis

DOI: 10.1016/S0304-3894(02)00318-7

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摘要: Commercial methyl-parathion (MeP) was detoxified using an electrochemical method that employed a Ti/Pt anode and stainless steel 304 as cathode. Sodium chloride added electrolyte the mixture passed through electrolytic cell for 2 h. Due to strong oxidizing potential of produced chemicals, organic pollutants were wet oxidized carbon dioxide water. A number experiments run at laboratory scale. Reductions COD BOD(5) both over 80% mean energy consumption 18-8 kWh per kg(-1) reduced (COD(r)). The degradation MeP more effective when pH brine solution in acid range than it alkaline range. From results can be concluded electrolysis could used oxidation pre-treatment stage detoxification toxic wastes with MeP.

参考文章(16)
Robert I. Krieger, HANDBOOK OF PESTICIDE TOXICOLOGY : Academic Press. ,(2001)
Raymond C. Loehr, Pollution control for agriculture ,(1977)
Andrew Eaton, A.E. Greenberg, Lenore S. Clesceri, Standard methods for the examination of water and wastewater Published in <b>1998</b> in Washington DC) by American public health association. ,(1992)
Dionissios Mantzavinos, David M.P Burrows, Roy Willey, Giuseppe Lo Biundo, Sheng F Zhang, Andrew G Livingston, Ian S Metcalfe, Chemical treatment of an anionic surfactant wastewater: Electrospray-MS studies of intermediates and effect on aerobic biodegradability. Water Research. ,vol. 35, pp. 3337- 3344 ,(2001) , 10.1016/S0043-1354(01)00066-5
Li-Choung Chiang, Juu-En Chang, Ten-Chin Wen, Indirect oxidation effect in electrochemical oxidation treatment of landfill leachate Water Research. ,vol. 29, pp. 671- 678 ,(1995) , 10.1016/0043-1354(94)00146-X
A. Vlyssides, P. Karlis, M. Loizidou, A. Zorpas, D. Arapoglou, Treatment of Leachate from a Domestic Solid Waste Sanitary Landfill by an Electrolysis System Environmental Technology. ,vol. 22, pp. 1467- 1476 ,(2001) , 10.1080/09593332208618184
M. Della Monica, A. Agostiano, A. Ceglie, An electrochemical sewage treatment process Journal of Applied Electrochemistry. ,vol. 10, pp. 527- 533 ,(1980) , 10.1007/BF00614086
Ch. Comninellis, C. Pulgarin, Anodic oxidation of phenol for waste water treatment Journal of Applied Electrochemistry. ,vol. 21, pp. 703- 708 ,(1991) , 10.1007/BF01034049