Characterization of hydrogen adsorption in platinum-doped microporous carbon with varied catalytic properties
作者： Chien-Hung Chen , Ming-Sheng Yu , Cheng-Si Tsao , Haw-Yeu Chuang , Huan-Hsiung Tseng
DOI: 10.1016/J.MICROMESO.2011.11.041
关键词:
摘要: Abstract The effect of the catalytic property platinum (Pt) on hydrogen adsorption activated carbon (AC) via spillover was investigated. clearly identified from both isotherms and kinetics. Factors, including Pt particle size, loading content AC nature, in platinum-doped (Pt/AC) were considered this study. experiments performed using a volumetric apparatus at room temperature (RT) low pressure (∼0.1 MPa). In study, enhancement factors 16–145% due to obtained for Pt/AC samples because difference textural properties receptors. rate spilt-over is strongly dominated by surface sites as functions crystallite size deposition type (with or without aggregation). When amounted below 0.011 mmol/g, an insignificant observed Pt/AC.
elsevier.com
sci-hub.se 参考文章(30)
Hao Chen, Ralph T. Yang, Catalytic effects of TiF3 on hydrogen spillover on Pt/carbon for hydrogen storage. Langmuir. ,vol. 26, pp. 15394- 15398 ,(2010) , 10.1021/LA100172B
J FREEL, Chemisorption on supported platinum II. Stoichiometry for hydrogen, oxygen and carbon monoxide Journal of Catalysis. ,vol. 25, pp. 149- 160 ,(1972) , 10.1016/0021-9517(72)90212-6
J FREEL, Chemisorption on supported platinum I. Evaluation of a pulse method Journal of Catalysis. ,vol. 25, pp. 139- 148 ,(1972) , 10.1016/0021-9517(72)90211-4
Alejandro Ansón, Esperanza Lafuente, Esteban Urriolabeitia, Rafael Navarro, Ana M. Benito, Wolfgang K. Maser, M. Teresa Martínez, Hydrogen capacity of palladium-loaded carbon materials. Journal of Physical Chemistry B. ,vol. 110, pp. 6643- 6648 ,(2006) , 10.1021/JP057206C
Anthony J. Lachawiec, Gongshin Qi, Ralph T. Yang, Hydrogen storage in nanostructured carbons by spillover: bridge-building enhancement. Langmuir. ,vol. 21, pp. 11418- 11424 ,(2005) , 10.1021/LA051659R
Andrew J. Robell, E. V. Ballou, Michel Boudart, Surface Diffusion of Hydrogen on Carbon The Journal of Physical Chemistry. ,vol. 68, pp. 2748- 2753 ,(1964) , 10.1021/J100792A003
Chang-Keun Back, Giselle Sandí, Jai Prakash, Jasmina Hranisavljevic, Hydrogen sorption on palladium-doped sepiolite-derived carbon nanofibers. Journal of Physical Chemistry B. ,vol. 110, pp. 16225- 16231 ,(2006) , 10.1021/JP061925P
J Ozaki, W Ohizumi, A Oya, MJ Illan-Gomez, MC Roman-Martinez, A Linares-Solano, None, Comparison of hydrogen adsorption abilities of platinum-loaded carbon fibers prepared using two different methods Carbon. ,vol. 38, pp. 778- 780 ,(2000) , 10.1016/S0008-6223(00)00033-6
Yingwei Li, Ralph T. Yang, Significantly enhanced hydrogen storage in metal-organic frameworks via spillover. Journal of the American Chemical Society. ,vol. 128, pp. 726- 727 ,(2006) , 10.1021/JA056831S
Nicholas R. Stuckert, Lifeng Wang, Ralph T. Yang, Characteristics of hydrogen storage by spillover on Pt-doped carbon and catalyst-bridged metal organic framework. Langmuir. ,vol. 26, pp. 11963- 11971 ,(2010) , 10.1021/LA101377U