Evidence for single electron transfer (SET) pathway in the reaction of primary alkylcadmium reagents with p-benzoquinone
作者： Mansour Shahidzadeh , Mehdi Ghandi
DOI: 10.1016/S0022-328X(00)00898-6
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摘要: Abstract The reaction of primary alkylcadmium reagents with p -benzoquinone at various conditions was studied. On the basis our results, proceeds through a SET mechanism that forms loose and tight intermediates, which produce quinole ( 1 ) substituted hydroquinone 2 ). In both cases, 3 is obtained in different yields.
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