Absolute rate constant determinations for the deactivation of O(1D) by time resolved decay of O(1D) →O(3P) emission
作者： J. A. Davidson , C. M. Sadowski , H. I. Schiff , G. E. Streit , Carleton J. Howard
DOI: 10.1063/1.431910
关键词:
摘要: Absolute rate constants for the deactivation of O(1D) atoms by some atmospheric gases have been determined observing time resolved emission at 630 nm. were produced dissociation ozone via repetitive laser pulses 266 relaxation (×10−10 cm3 molecule−1⋅s−1) N2(0.30±0.01), O2(0.41±0.05), CO2(1.2±0.09), O3(2.4±0.1), H2(1.3±0.05), D2(1.3±0.05), CH4(1.3±0.3), HCl(1.4±0.3), NH3 (3.4±0.3), H2O(2.1±1.0), N2O(1.4±0.1), and Ne (<0.0013) are reported 298 K. The results obtained compared with previous relative absolute measurements in literature.
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