Ring selectivity and migratory aptitude of Cp*Ru+ complexation to acecorannuleneElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b316061k/

作者: T. Jon Seiders , Kim K. Baldridge , Joseph M. O'Connor , Jay S. Siegel

DOI: 10.1039/B316061K

关键词:

摘要: Synthesis and spectral characterization of acecorannulene CpRu+ complexes, in combination with ab initio quantum chemical computations, leads to the hypothesis that η6-metal binding prefers exo face region least curvature.

参考文章(21)
Axel D. Becke, Density-functional thermochemistry. III. The role of exact exchange Journal of Chemical Physics. ,vol. 98, pp. 5648- 5652 ,(1993) , 10.1063/1.464913
Kwangyeol Lee, Hyunjoon Song, Joon T. Park, [60]fullerene--metal cluster complexes: novel bonding modes and electronic communication. Accounts of Chemical Research. ,vol. 36, pp. 78- 86 ,(2003) , 10.1021/AR020149A
P. Jeffrey Hay, Willard R. Wadt, Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals Journal of Chemical Physics. ,vol. 82, pp. 299- 310 ,(1985) , 10.1063/1.448975
T. Jon Seiders, Eric L. Elliott, Gunther H. Grube, Jay S. Siegel, Synthesis of Corannulene and Alkyl Derivatives of Corannulene Journal of the American Chemical Society. ,vol. 121, pp. 7804- 7813 ,(1999) , 10.1021/JA991310O
Dale E. Wheeler, Scott T. Hill, John M. Carey, Coordination site preference study of Cp∗Ru+ in monosubstituted naphthalene complexes Inorganica Chimica Acta. ,vol. 249, pp. 157- 161 ,(1996) , 10.1016/0020-1693(96)05091-8
Mitch Nambu, Debra L. Mohler, Kenneth Hardcastle, Kim K. Baldridge, Jay S. Siegel, Synthesis, structure, and dynamics of endo-(starphenylene)chromium tricarbonyl derivatives: observation of metal-arene migration and hindered metal-tripod rotation Journal of the American Chemical Society. ,vol. 115, pp. 6138- 6142 ,(1993) , 10.1021/JA00067A032
T. Jon Seiders, Kim K. Baldridge, Joseph M. O'Connor, Jay S. Siegel, Hexahapto Metal Coordination to Curved Polyaromatic Hydrocarbon Surfaces: The First Transition Metal Corannulene Complex Journal of the American Chemical Society. ,vol. 119, pp. 4781- 4782 ,(1997) , 10.1021/JA964380T
P. J. Fagan, J. C. Calabrese, B. Malone, The Chemical Nature of Buckminsterfullerene (C60) and the Characterization of a Platinum Derivative Science. ,vol. 252, pp. 1160- 1161 ,(1991) , 10.1126/SCIENCE.252.5009.1160
Celedonio M. Alvarez, Robert J. Angelici, Andrzej Sygula, Renata Sygula, Peter W. Rabideau, η6-Corannulene Buckybowl Complexes of Iridium, Including Ring-to-Ring Migration Organometallics. ,vol. 22, pp. 624- 626 ,(2003) , 10.1021/OM021012R