Atomic Layer Deposition Synthesis of Alumina-Modified SBA-15 and its Catalytic Reactivity Toward Methanol Dehydration

作者: Yucai Xu , Ping Yang , Hailu Zhang , Zongwu Deng

DOI: 10.1080/15533174.2011.591340

关键词:

摘要: Mesoporous material SBA-15 was modified by alumina via an atomic layer deposition method and used for the reaction of methanol dehydration. The samples were characterized x-ray powder diffraction, transmission electron microscopy, solid-state nuclear magnetic resonance, Brunauer-Emmett-Teller (BET) methods. results revealed that Al had been successfully incorporated into framework after modification. Both Bronsted Lewis acid sites coexist on alumina-modified surface. with Al2O3/SiO2 ratios 8 wt% has higher activity compared titania- tungsten oxide-modified SBA-15.

参考文章(23)
Ellen Van Bavel, Vera Meynen, Pegie Cool, Kurt Lebeau, Etienne F. Vansant, Adsorption of hydrocarbons on mesoporous SBA-15 and PHTS materials. Langmuir. ,vol. 21, pp. 2447- 2453 ,(2005) , 10.1021/LA0474417
Satoshi Sato, Toshiaki Sodesawa, Fumio Nozaki, Hiroshi Shoji, Solid-state NMR of silica—alumina prepared by chemical vapor deposition Journal of Molecular Catalysis. ,vol. 66, pp. 343- 355 ,(1991) , 10.1016/0304-5102(91)80026-Y
Jack H. Lunsford, William P. Rothwell, Wenxia Shen, Acid sites in zeolite Y: a solid-state NMR and infrared study using trimethylphosphine as a probe molecule Journal of the American Chemical Society. ,vol. 107, pp. 1540- 1547 ,(1985) , 10.1021/JA00292A015
Wang Ying, Li Genbao, Zhu Wei, Zhou Longbao, Study on the application of DME/diesel blends in a diesel engine Fuel Processing Technology. ,vol. 89, pp. 1272- 1280 ,(2008) , 10.1016/J.FUPROC.2008.05.023
Maria D. Gracia, Alina M. Balu, Juan M. Campelo, Rafael Luque, Jose M. Marinas, Antonio A. Romero, Evidences of the in situ generation of highly active Lewis acid species on Zr-SBA-15 Applied Catalysis A-general. ,vol. 371, pp. 85- 91 ,(2009) , 10.1016/J.APCATA.2009.09.033
Hsien-Ming Kao, Pai-Ching Chang, Yun-Wen Liao, Lung-Ping Lee, Chu-Hua Chien, Solid-state NMR characterization of the acid sites in cubic mesoporous Al-MCM-48 materials using trimethylphosphine oxide as a 31P NMR probe Microporous and Mesoporous Materials. ,vol. 114, pp. 352- 364 ,(2008) , 10.1016/J.MICROMESO.2008.01.021
Sadanobu Sumiya, Yasunori Oumi, Toshiya Uozumi, Tsuneji Sano, Characterization of AlSBA-15 prepared by post-synthesisalumination with trimethylaluminium Journal of Materials Chemistry. ,vol. 11, pp. 1111- 1115 ,(2001) , 10.1039/B008168J