Dysprosium Thiocyanate Complexes with s-Triazine
作者： S. P. Petrosyants , A. B. Ilyukhin , K. A. Babeshkin , E. V. Belova , A. V. Gavrikov
DOI: 10.1134/S1070328419080062
关键词:
摘要: The reaction of Dy(NCS)3 · 6H2O with 2,4,6-tris(2-pyridyl)-s-triazine (Tptz) in МеОН, MeCN, and H2O affords mononuclear neutral ionic thiocyanate complexes tridentate ligand Tptz: [Dy(H2O)(MeOH)(Tptz)(NCS)3] Tptz (I), [Dy(Tptz)2(NCS)3] MeCN (II), [Dy(H2O)3-(Tptz)(NCS)2] NCS 1.5H2O 1.25MeOH (III). Structural features the synthesized compounds are determined using powder XRD, IR spectroscopy, thermoanalytical methods (thermogravimetry differential scanning calorimetry). Compounds II III exhibit properties single-molecule magnets.
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