Bi-functional heterogeneous catalysts for carbon dioxide conversion: enhanced performances at low temperature
作者： Adrien Comès , Xavier Collard , Luca Fusaro , Luciano Atzori , M. Giorgia Cutrufello
DOI: 10.1039/C8RA03878C
关键词:
摘要: Novel heterogeneous bi-functional catalysts bearing tin or zinc inserted as single sites within the silica architecture acting acid centres and decorated with imidazolium moieties nucleophile source were successfully synthesized. The materials extensively characterized via various techniques including N2 physisorption, solid state nuclear magnetic resonance, X-ray photoelectron spectroscopy, transmission electron microscopy adsorption microcalorimetry. solids tested for conversion of carbon dioxide, selecting synthesis styrene carbonate target reaction. Both exhibited improved performances compared to analogous functionalized sole salt well other reported in literature. Sn-based catalyst displayed excellent also presence epoxides. In all experiments allowed reducing reaction temperature below 150 °C. glycidol was decreased down 30 short protocol catalysts, together 100% atom economy low temperature, make entire process highly sustainable. Moreover, stable under selected conditions reusable multiple catalytic cycles.
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Philip L. Llewellyn, Emily Bloch, Sandrine Bourrelly, Surface Area/Porosity, Adsorption, Diffusion John Wiley & Sons, Ltd. pp. 853- 879 ,(2012) , 10.1002/9783527645329.CH19
Carmela Aprile, Hermenegildo Garcia, Paolo P. Pescarmona, Synthesis and Characterization of Supported Chiral Catalysts Catalytic methods in asymmetric synthesis: advanced materials, techniques, and applications. pp. 177- 208 ,(2011) , 10.1002/9781118087992.CH3
Lucia A. Bivona, Ornella Fichera, Luca Fusaro, Francesco Giacalone, Mireia Buaki-Sogo, Michelangelo Gruttadauria, Carmela Aprile, A polyhedral oligomeric silsesquioxane-based catalyst for the efficient synthesis of cyclic carbonates Catalysis Science & Technology. ,vol. 5, pp. 5000- 5007 ,(2015) , 10.1039/C5CY00830A
Michael R. Kember, Antoine Buchard, Charlotte K. Williams, Catalysts for CO2/epoxide copolymerisation Chemical Communications. ,vol. 47, pp. 141- 163 ,(2011) , 10.1039/C0CC02207A
Xavier Collard, Pierre Louette, Sonia Fiorilli, Carmela Aprile, High surface area zincosilicates as efficient catalysts for the synthesis of ethyl lactate: an in-depth structural investigation Physical Chemistry Chemical Physics. ,vol. 17, pp. 26756- 26765 ,(2015) , 10.1039/C5CP03577E
G. Colón, I. Ferino, E. Rombi, E. Selli, L. Forni, P. Magnoux, M. Guisnet, Liquid-phase alkylation of naphthalene by isopropanol over zeolites. Part 1: HY zeolites Applied Catalysis A: General. ,vol. 168, pp. 81- 92 ,(1998) , 10.1016/S0926-860X(97)00346-3
Paola Agrigento, Syed M. Al-Amsyar, Benjamin Sorée, Masoumeh Taherimehr, Michelangelo Gruttadauria, Carmela Aprile, Paolo P. Pescarmona, Synthesis and high-throughput testing of multilayered supported ionic liquid catalysts for the conversion of CO2 and epoxides into cyclic carbonates Catalysis Science & Technology. ,vol. 4, pp. 1598- 1607 ,(2014) , 10.1039/C3CY01000G
P. Shah, A.V. Ramaswamy, K. Lazar, Veda Ramaswamy, Direct hydrothermal synthesis of mesoporous Sn-SBA-15 materials under weak acidic conditions Microporous and Mesoporous Materials. ,vol. 100, pp. 210- 226 ,(2007) , 10.1016/J.MICROMESO.2006.10.042
Christophe Cossement, Jacques Darville, Jean-Marie Gilles, Janos B. Nagy, Christian Fernandez, Jean-Paul Amoureux, Chemical shift anisotropy and indirect coupling in SnO2 and SnO Magnetic Resonance in Chemistry. ,vol. 30, pp. 263- 270 ,(1992) , 10.1002/MRC.1260300313
Sharon E. Ashbrook, Scott Sneddon, New methods and applications in solid-state NMR spectroscopy of quadrupolar nuclei. Journal of the American Chemical Society. ,vol. 136, pp. 15440- 15456 ,(2014) , 10.1021/JA504734P