Dispersion control and nematic ordering of Ni/Al layered double hydroxide suspensions

作者: Lingyu Luan , Shangying Liu , Dejun Sun

DOI: 10.1016/J.JSSC.2009.03.006

关键词:

摘要: Abstract In this paper, we report the preparation of aqueous suspensions Ni/Al layered double hydroxide (LDH) nanoparticles by a non-steady co-precipitation followed peptization. By choosing suitable peptization temperature and time, well-dispersed were obtained. Meanwhile, particle size, shape size polydispersity can be efficiently controlled. Nematic ordering is observed in colloidal LDH confirmed birefringence observations SAXS measurements. Furthermore, showed that sol–gel transition takes place after liquid crystalline phase concentrated suspensions. The absence isotropic–nematic separation attributed to fact nematic droplets are too small settle bottom cuvette.

参考文章(39)
Fei Yang, Shangying Liu, Jian Xu, Qiang Lan, Fang Wei, Dejun Sun, Pickering emulsions stabilized solely by layered double hydroxides particles: the effect of salt on emulsion formation and stability. Journal of Colloid and Interface Science. ,vol. 302, pp. 159- 169 ,(2006) , 10.1016/J.JCIS.2006.06.015
Maurizio Bellotto, Bernadette Rebours, Olivier Clause, John Lynch, Dominique Bazin, Eric Elkaïm, A Reexamination of Hydrotalcite Crystal Chemistry The Journal of Physical Chemistry. ,vol. 100, pp. 8527- 8534 ,(1996) , 10.1021/JP960039J
D. van der Beek, H. N. W Lekkerkerker, Nematic ordering vs. gelation in suspensions of charged platelets EPL. ,vol. 61, pp. 702- 707 ,(2003) , 10.1209/EPL/I2003-00132-1
Martin A. Bates, Influence of particle shape on the nematic—isotropic transition of colloidal platelet systems Journal of Chemical Physics. ,vol. 111, pp. 1732- 1736 ,(1999) , 10.1063/1.479433
David van der Beek, Henk N. W. Lekkerkerker, Liquid Crystal Phases of Charged Colloidal Platelets Langmuir. ,vol. 20, pp. 8582- 8586 ,(2004) , 10.1021/LA049455I
A. Mourchid, E. Lécolier, H. Van Damme, P. Levitz, On Viscoelastic, Birefringent, and Swelling Properties of Laponite Clay Suspensions: Revisited Phase Diagram Langmuir. ,vol. 14, pp. 4718- 4723 ,(1998) , 10.1021/LA980117P
Peizhi Guo, Dejun Sun, Jie Zhang, Chunguang Zhang, Studies on synthesis of MMH and rheological properties of concentrated MMH dispersions Chemistry Letters. ,vol. 32, pp. 250- 251 ,(2003) , 10.1246/CL.2003.250
Laurent J. Michot, Jaafar Ghanbaja, Viyaada Tirtaatmadja, Peter J. Scales, Sol−Gel Transitions in Aqueous Suspensions of Synthetic Takovites. The Role of Hydration Properties and Anisotropy Langmuir. ,vol. 17, pp. 2100- 2105 ,(2001) , 10.1021/LA001579H
Yun Zhao, Feng Li, Rui Zhang, David G. Evans, Xue Duan, Preparation of Layered Double-Hydroxide Nanomaterials with a Uniform Crystallite Size Using a New Method Involving Separate Nucleation and Aging Steps Chemistry of Materials. ,vol. 14, pp. 4286- 4291 ,(2002) , 10.1021/CM020370H