A new type of electrochemical cell based on the configuration NaI |PEG| I2
作者： R. Chandrasekaran , S. Selladurai
DOI: 10.1007/BF02374069
关键词:
摘要: Different operating conditions of a new electrochemical cell based on sodium iodide and polyethylene glycol (PEG) polymer as separator well conducting electrolyte is reported. Five types cells were fabricated using pure NaI, PC+NaI, water+NaI dil. HCl+NaI H2SO4+NaI in the configuration NaI |PEG| I2 |PEG|s I2+C. Their discharge characteristics studied at room temperature (33 °C). From parameters, it found that open circuit voltage ranges from 648 mV to 1023 short current 29 µA 4.8 mA.
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sci-hub.se 参考文章(17)
Suresh Chandra, Amulya L. Laskar, Superionic solids and solid electrolytes : recent trends Academic Press. ,(1989)
Y PAK, K ADAMIC, S GREENBAUM, M WINTERSGILL, J FONTANELLA, C COUGHLIN, Complex impedance and multifrequency 23Na NMR study of poly(propylene oxide) complexed with NaB (C6H5)4 Solid State Ionics. ,vol. 45, pp. 277- 284 ,(1991) , 10.1016/0167-2738(91)90162-5
T. Sreekanth, M. Jaipal Reddy, S. Ramalingaiah, U.V. Subba Rao, Ion-conducting polymer electrolyte based on poly (ethylene oxide) complexed with NaNO3 salt-application as an electrochemical cell Journal of Power Sources. ,vol. 79, pp. 105- 110 ,(1999) , 10.1016/S0378-7753(99)00051-8
D.F. Shriver, B.L. Papke, M.A. Ratner, R. Dupon, T. Wong, M. Brodwin, Structure and ion transport in polymer-salt complexes Solid State Ionics. ,vol. 5, pp. 83- 88 ,(1981) , 10.1016/0167-2738(81)90199-5
S. G. Greenbaum, Y. S. Pak, M. C. Wintersgill, J. J. Fontanella, J. W. Schultz, C. G. Andeen, NMR, DSC, DMA, and High Pressure Electrical Conductivity Studies in PPO Complexed with Sodium Perchlorate Journal of The Electrochemical Society. ,vol. 135, pp. 235- 238 ,(1988) , 10.1149/1.2095562
D. Fauteux, M. D. Lupien, C. D. Robitaille, Phase diagram, conductivity, and transference number of PEO-NaI electrolytes Journal of The Electrochemical Society. ,vol. 134, pp. 2761- 2767 ,(1987) , 10.1149/1.2100283
Mark A. Ratner, Duward F. Shriver, Ion Transport in Solvent-Free Polymers Chemical Reviews. ,vol. 88, pp. 109- 124 ,(1988) , 10.1021/CR00083A006
S GREENBAUM, NMR, DSC and electrical conductivity studies of MEEP complexed with NaCF3SO3 Solid State Ionics. pp. 1042- 1046 ,(1988) , 10.1016/0167-2738(88)90328-1
J FONTANELLA, M MCLIN, M WINTERSGILL, J CALAME, S GREENBAUM, Electrical impedance studies of acid form NAFION® membranes Solid State Ionics. ,vol. 66, pp. 1- 4 ,(1993) , 10.1016/0167-2738(93)90020-4
B STEELE, G LAGOS, P SPURDENS, C FORSYTH, A FOORD, Behaviour of LixV6O13 and LixTiS2 composite electrodes incorporating polyethylene oxide based electrolytes Solid State Ionics. pp. 391- 398 ,(1983) , 10.1016/0167-2738(83)90265-5