Sample Preparation for Analysis of Chemicals Related to the Chemical Weapons Convention

作者: Marja-Leena Kuitunen

DOI: 10.1002/9780470027318.A0410

关键词:

摘要: This article discusses the preparation of environmental samples to be analyzed for chemicals related chemical weapons convention (CWC), where analysis takes place on-site or off-site by gas chromatography (GC) liquid (LC) as an introduction technique spectrometers capillary zone electrophoresis (CZE). The specific sample methods required spectroscopic techniques such Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopy are dealt with in separate articles. Preparations analytical from air, aqueous (water), soil, active charcoal, wipe, concrete, paint, rubber, other polymeric presented section 2, preparations wipe analysis, covered 3. described standard operating procedures (SOPs) international organization responsible verifying Convention (Technical Secretariat Organization Prohibition Chemical Weapons) those corresponding recommended (ROPs). Section 4 examines question quality control (QC) 5 important matter safety handling containing CWC-related chemicals. 6 reports on use comparison proficiency tests.

参考文章(19)
John Aasulf T⊘rnes, Aase Mari Opstad, Bj⊘rn Arne Johnsen, Use of Solid-Phase Extraction in Determination of Chemical Warfare Agents International Journal of Environmental Analytical Chemistry. ,vol. 44, pp. 227- 231 ,(1991) , 10.1080/03067319108027555
Charles E. Kientz, Albert Verweij, Gerhardus J. De Jong, Udo A. Th. Brinkman, Verification of nonproduction of chemical warfare agents: I. Determination of organophosphorus compounds by microcolumn liquid chromatography with flame photometric or thermionic detection Journal of Microcolumn Separations. ,vol. 4, pp. 465- 475 ,(1992) , 10.1002/MCS.1220040602
Vesa M. A. Häkkinen, Analysis of chemical warfare agents in water by solid phase extraction and two-channel capillary gas chromatography Journal of High Resolution Chromatography. ,vol. 14, pp. 811- 815 ,(1991) , 10.1002/JHRC.1240141207
Z. Witkiewicz, M. Mazurek, J. Szulc, Chromatographic analysis of chemical warfare agents Journal of Chromatography A. ,vol. 503, pp. 293- 357 ,(1990) , 10.1016/S0021-9673(01)81514-4
Marja-Leena Kuitunen, Kari Hartonen, Marja-Liisa Riekkola, Analysis of chemical warfare agents in soil samples by off-line supercritical fluid extraction and capillary gas chromatography Journal of Microcolumn Separations. ,vol. 3, pp. 505- 512 ,(1991) , 10.1002/MCS.1220030605
E.R.J. Wils, A.G. Hulst, Determination of organophosphorus acids by thermospray liquid chromatography-mass spectrometry Journal of Chromatography A. ,vol. 454, pp. 261- 272 ,(1988) , 10.1016/S0021-9673(00)88619-7
Charles E. Kientz, Albert Verweij, Gerhardus J. De Jong, Udo A. Th. Brinkman, Verification of nonproduction of chemical warfare agents: II. Large volume injections in microcolumn liquid chromatography using flame photometric detection Journal of Microcolumn Separations. ,vol. 4, pp. 477- 483 ,(1992) , 10.1002/MCS.1220040603