Synthesis and characterization of cyclometallated palladium(II) and platinum(II) complexes with amide-thiolate ligands
作者： Tatsuya Kawamoto , Satoko Suzuki , Takumi Konno
DOI: 10.1016/J.JORGANCHEM.2006.08.051
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摘要: Abstract The redox reaction of bis(2-benzamidophenyl) disulfide (H 2 L-LH ) with [Pd(PPh 3 4 ] in a 1:1 ratio gave mononuclear and dinuclear palladium(II) complexes 2-benzamidobenzenethiolate L − ), [Pd(H L- S (PPh ( 1 [Pd (μ-H ). A similar [Pt(PPh produced only the corresponding platinum(II) complex, [Pt(H Treatment these KOH led to formation cyclometallated complexes, [Pd(L- C , N )(PPh )] ([ [Pt(L- 5 molecular structures [ were determined by X-ray crystallography.
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