Synthesis of dibenzo-[b,f][1,5]diazocine-based hosts and their assembly behaviors with C60

作者: Yi Jiang , Xiao Wang , Zengjian An , Xiaobo Wan

DOI: 10.1016/J.TETLET.2014.04.094

关键词:

摘要: Diaryl[b,f][1,5]diazocine-based macrocycles 5 and 6 with inner cavities have been synthesized via Hay coupling method. Single crystal of shows that it forms a dimeric aggregate the weak intermolecular interactions between two adjacent rings, which is rarely reported in such macrocycles. Moreover, SEM results reveal both assemble C60 to form well-ordered fullerene-based nano-rod structures.

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