Characterization of Epoxy Functionalized Graphite Nanoparticles and the Physical Properties of Epoxy Matrix Nanocomposites

作者: Sandi G. Miller , Jonathan L. Bauer , Michael J. Maryanski , Paula J. Heimann , Jeremy P. Barlow

DOI: 10.1016/J.COMPSCITECH.2010.02.023

关键词:

摘要: Abstract This work presents a novel approach to the functionalization of graphite nanoparticles. The technique provides mechanism for covalent bonding between filler and matrix, with minimal disruption sp 2 hybridization pristine graphene sheet. Functionalization proceeded by covalently an epoxy monomer surface expanded graphite, via coupling agent, such that concentration was measured as approximately 4 wt.%. impact dispersing this material into resin evaluated respect mechanical properties electrical conductivity graphite–epoxy nanocomposite. At loading low 0.5 wt.%, increased five orders magnitude relative base resin. yield strength 30% Young’s modulus 50%. These results were realized without compromise toughness.

参考文章(29)
José S Casas, Alfonso Castiñeiras, Nuria Playá, Agustı́n Sánchez, José Sordo, José Ma Varela, Ezequiel M Vázquez-López, Methylmercury and dimethylthallium complexes of 5-(4′-dimethylaminobenzylidene)-2-thiohydantoin (HDABTd) Polyhedron. ,vol. 18, pp. 3653- 3659 ,(1999) , 10.1016/S0277-5387(99)00298-3
Ioana Dumitrescu, Neil R. Wilson, Julie V. Macpherson, Functionalizing Single-Walled Carbon Nanotube Networks: Effect on Electrical and Electrochemical Properties Journal of Physical Chemistry C. ,vol. 111, pp. 12944- 12953 ,(2007) , 10.1021/JP067256X
R BAGWELL, J MCMANAMAN, R WETHERHOLD, Short shaped copper fibers in an epoxy matrix : Their role in a multifunctional composite Composites Science and Technology. ,vol. 66, pp. 522- 530 ,(2006) , 10.1016/J.COMPSCITECH.2005.06.005
S. Shenogin, A. Bodapati, L. Xue, R. Ozisik, P. Keblinski, Effect of chemical functionalization on thermal transport of carbon nanotube composites Applied Physics Letters. ,vol. 85, pp. 2229- 2231 ,(2004) , 10.1063/1.1794370
Peng Cheng Ma, Jang-Kyo Kim, Ben Zhong Tang, Effects of silane functionalization on the properties of carbon nanotube/epoxy nanocomposites Composites Science and Technology. ,vol. 67, pp. 2965- 2972 ,(2007) , 10.1016/J.COMPSCITECH.2007.05.006
E. Lafuente, M.A. Callejas, R. Sainz, A.M. Benito, W.K. Maser, M.L. Sanjuán, D. Saurel, J.M. de Teresa, M.T. Martínez, The influence of single-walled carbon nanotube functionalization on the electronic properties of their polyaniline composites Carbon. ,vol. 46, pp. 1909- 1917 ,(2008) , 10.1016/J.CARBON.2008.07.039
Fubing Peng, Fusheng Pan, Honglei Sun, Lianyu Lu, Zhongyi Jiang, Novel nanocomposite pervaporation membranes composed of poly(vinyl alcohol) and chitosan-wrapped carbon nanotube Journal of Membrane Science. ,vol. 300, pp. 13- 19 ,(2007) , 10.1016/J.MEMSCI.2007.06.008
Elena Bekyarova, Mikhail E. Itkis, Nelson Cabrera, Bin Zhao, Aiping Yu, Junbo Gao, Robert C. Haddon, Electronic Properties of Single-Walled Carbon Nanotube Networks Journal of the American Chemical Society. ,vol. 127, pp. 5990- 5995 ,(2005) , 10.1021/JA043153L
A.G. Osorio, I.C.L. Silveira, V.L. Bueno, C.P. Bergmann, H2SO4/HNO3/HCl—Functionalization and its effect on dispersion of carbon nanotubes in aqueous media Applied Surface Science. ,vol. 255, pp. 2485- 2489 ,(2008) , 10.1016/J.APSUSC.2008.07.144