Comparison of the stability and reactivity of achiral versus chiral nonheme oxoiron(IV) complexes supported by pentadentate N5 ligands in oxygen-atom and hydrogen-atom transfer reactions
作者： Dóra Lakk-Bogáth , Gábor Speier , József Kaizer
DOI: 10.1016/J.INOCHE.2019.107446
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摘要: Abstract The present work is undertaken to examine the stability, and reactivity of chiral [FeIV(N2Py2Q*)(O)]2+ (N2Py2Q* = N,N.bis(2-quinolylmethyl)-1,2-di(2-pyridyl)ethylamine) complex, along with mechanistic details thioanisole, benzylalcohol, hydrocarbon oxidation in comparison [FeIV(N4Py*)(O)]2+ (N4Py* = N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine) related achiral FeIVO systems as a test before its utilization an enantioselective synthesis.
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