Effects of oversized solutes on radiation-induced segregation in austenitic stainless steels

作者: M.J. Hackett , J.T. Busby , M.K. Miller , G.S. Was

DOI: 10.1016/J.JNUCMAT.2009.02.010

关键词:

摘要: Zirconium or hafnium additions to austenitic stainless steels caused a reduction in grain boundary Cr depletion after proton irradiations for up 3 dpa at 400 °C and 1 500 °C. The predictions of radiation-induced segregation (RIS) model were also consistent with experiments showing greater effectiveness Zr relative Hf due larger binding energy. However, the showed that solute disappeared above loss increasing dose is attributed amount oversized from matrix growth carbide precipitates. Atom probe tomography measurements indicated solution as function irradiation dose. observations supported by diffusion analysis suggesting significant vacancy flux precipitate surfaces occurs on time scales irradiations. With decrease available solution, improved agreement between RIS solute-vacancy trapping process, mechanism enhanced recombination suppression RIS.

参考文章(32)
Daniel P. Abraham, Sean M. McDeavitt, Jangyul Park, Microstructure and phase identification in type 304 stainless steel-zirconium alloys Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science. ,vol. 27, pp. 2151- 2159 ,(1996) , 10.1007/BF02651870
J Gan, E.P Simonen, S.M Bruemmer, L Fournier, B.H Sencer, G.S Was, The effect of oversized solute additions on the microstructure of 316SS irradiated with 5 MeV Ni++ ions or 3.2 MeV protons Journal of Nuclear Materials. ,vol. 325, pp. 94- 106 ,(2004) , 10.1016/J.JNUCMAT.2003.11.002
M KRCMAR, C FU, A JANOTTI, R REED, Diffusion rates of 3d transition metal solutes in nickel by first-principles calculations Acta Materialia. ,vol. 53, pp. 2369- 2376 ,(2005) , 10.1016/J.ACTAMAT.2005.01.044
M.K. Miller, K.F. Russell, Atom probe specimen preparation with a dual beam SEM/FIB miller. Ultramicroscopy. ,vol. 107, pp. 761- 766 ,(2007) , 10.1016/J.ULTRAMIC.2007.02.023
Takahiko Kato, Heishichiro Takahashi, Masakiyo Izumiya, Grain boundary segregation under electron irradiation in austenitic stainless steels modified with oversized elements Journal of Nuclear Materials. ,vol. 189, pp. 167- 174 ,(1992) , 10.1016/0022-3115(92)90529-T
N Sakaguchi, S Watanabe, H Takahashi, Effect of additional minor element on radiation-induced grain boundary segregation in austenitic stainless steel under electron irradiation Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 153, pp. 142- 146 ,(1999) , 10.1016/S0168-583X(98)00990-2
T.R. Allen, G.S. Was, Modeling radiation-induced segregation in austenitic Fe-Cr-Ni alloys Acta Materialia. ,vol. 46, pp. 3679- 3691 ,(1998) , 10.1016/S1359-6454(98)00019-6