Green Strategies for Molecularly Imprinted Polymer Development

作者: Raquel Viveiros , Sílvia Rebocho , Teresa Casimiro

DOI: 10.3390/POLYM10030306

关键词:

摘要: Molecular imprinting is a powerful technology to create artificial receptors within polymeric matrices. Although it was reported for the first time by Polyakov, eighty-four years ago, remains, nowadays, very challenging research area. Molecularly imprinted polymers (MIPs) have been successfully used in several applications where selective binding requirement, such as immunoassays, affinity separation, sensors, and catalysis. Conventional methods on MIP production still use large amounts of organic solvents which, allied with stricter legislation release chemicals environment presence impurities final materials, will boost, our opinion, new cleaner synthetic strategies, particular, application principles green chemistry engineering. Supercritical carbon dioxide, microwave, ionic liquids, ultrasound are some strategies which already applied production. These can improve properties, controlled morphology, homogeneity sites, absence solvents. This review intends give examples literature approaches development, from nano- micron-scale applications.

参考文章(156)
Albert R. Cunningham, Herbert S. Rosenkranz, Ying Ping Zhang, Gilles Klopman, Identification of 'genotoxic' and 'non-genotoxic' alerts for cancer in mice : the carcinogenic potency database Mutation Research. ,vol. 398, pp. 1- 17 ,(1998) , 10.1016/S0027-5107(97)00202-9
Anastasia Nikolaou, Sureyya Meric, Despo Fatta, Occurrence patterns of pharmaceuticals in water and wastewater environments. Analytical and Bioanalytical Chemistry. ,vol. 387, pp. 1225- 1234 ,(2007) , 10.1007/S00216-006-1035-8
Miles Weinberger, Leslie Hendeles, Theophylline in asthma. The New England Journal of Medicine. ,vol. 334, pp. 1380- 1388 ,(1996) , 10.1056/NEJM199605233342107
Liqing Wu, Baowei Sun, Yuanzong Li, Wenbao Chang, Study properties of molecular imprinting polymer using a computational approach Analyst. ,vol. 128, pp. 944- 949 ,(2003) , 10.1039/B212731H
Ian A. Nicholls, Håkan S. Andersson, Kerstin Golker, Henning Henschel, Björn C. G. Karlsson, Gustaf D. Olsson, Annika M. Rosengren, Siamak Shoravi, Subramanian Suriyanarayanan, Jesper G. Wiklander, Susanne Wikman, Rational design of biomimetic molecularly imprinted materials: theoretical and computational strategies for guiding nanoscale structured polymer development Analytical and Bioanalytical Chemistry. ,vol. 400, pp. 1771- 1786 ,(2011) , 10.1007/S00216-011-4935-1
Shifang Yuan, Qiliang Deng, Guozhen Fang, Jianhua Wu, Wangwang Li, Shuo Wang, Protein imprinted ionic liquid polymer on the surface of multiwall carbon nanotubes with high binding capacity for lysozyme. Journal of Chromatography B. ,vol. 960, pp. 239- 246 ,(2014) , 10.1016/J.JCHROMB.2014.04.021
Iren Bernus, Ronald G. Dickinson, Wayne D. Hooper, Mervyn J. Eadie, Dose-dependent metabolism of carbamazepine in humans Epilepsy Research. ,vol. 24, pp. 163- 172 ,(1996) , 10.1016/0920-1211(96)00011-3
Wei-Ming Yeh, Kuo-Chuan Ho, Amperometric morphine sensing using a molecularly imprinted polymer-modified electrode Analytica Chimica Acta. ,vol. 542, pp. 76- 82 ,(2005) , 10.1016/J.ACA.2005.01.071
Xiang-Jie Li, Xiu-Xiu Chen, Guan-Yin Sun, Yong Xin Zhao, Zhao-Sheng Liu, Haji Akber Aisa, Green synthesis and evaluation of isoquercitrin imprinted polymers for class-selective separation and purification of flavonol glycosides Analytical Methods. ,vol. 7, pp. 4717- 4724 ,(2015) , 10.1039/C5AY00892A