Diyne-Functionalized Fullerene Self-Assembly for Thin Film Solid-State Polymerization
作者： Jean-Nicolas Tisserant , Roland Hany , Eric Wimmer , Antoni Sánchez-Ferrer , Jozef Adamcik
DOI: 10.1021/MA401677V
关键词:
摘要: C-60 fullerene derivatives bearing aliphatic chains can self-assemble into versatile supramolecular structures. Cross-linking of such self-assembled morphologies is an attractive approach to enhance the structural stability these self-organized We describe synthesis a fimctionalized with single alkyl chain diacetylene moiety. In thin film, molecule self-assembles lamellar arrays. The character side attached key observed packing ability. stabilization proceeds through solid-state polymerization moieties. By blending fiillerene derivative cyanine dye, various nanostructured are obtained that be selectively stabilized by thermal polymerization. These films serve as basis for scaffolds find applications in optics and electronics.
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