A wide range kinetic modeling study of pyrolysis and oxidation of methyl butanoate and methyl decanoate – Note II: Lumped kinetic model of decomposition and combustion of methyl esters up to methyl decanoate
作者： Roberto Grana , Alessio Frassoldati , Chiara Saggese , Tiziano Faravelli , Eliseo Ranzi
DOI: 10.1016/J.COMBUSTFLAME.2012.02.027
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摘要: Abstract The aim of this work is to develop and discuss a lumped kinetic model simulate the pyrolysis combustion behavior methyl decanoate. Validation decanoate in very wide range conditions, with temperature ranging from 500 more than 2000 K, pressures up 16 bar equivalent ratios lean proved that, despite drastic simplifications, can properly reproduce experimental measurements as well an oxidation environment, both low regime flame conditions. This extension butanoate developed discussed first part [1] . Thus, also quite simply applied simulating intermediate esters, by using lever rule between two reference components. overall agreement encouraging lays basis for scheme soy rapeseed biodiesel fuels.
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