Diastereoselective Aminooxygenation and Diamination of Alkenes with Amidines by Hypervalent Iodine(III) Reagents.
作者： Hui Chen , Atsushi Kaga , Shunsuke Chiba
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摘要: Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine (III) reagents such as PhI (OCOR) 2 and PhI (NMs2) 2, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E-and Z-alkenes.
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sci-hub.se 参考文章(1)
Hui Chen, Atsushi Kaga, Shunsuke Chiba, Diastereoselective aminooxygenation and diamination of alkenes with amidines by hypervalent iodine(III) reagents. Organic Letters. ,vol. 16, pp. 6136- 6139 ,(2014) , 10.1021/OL503000C