Improving performance and reducing hysteresis in perovskite solar cells by using F8BT as electron transporting layer

作者: Lixiao Zhao , Xueyan Wang , Xiaodong Li , Wenjun Zhang , Xiaohui Liu

DOI: 10.1016/J.SOLMAT.2016.05.026

关键词:

摘要: Abstract A conjugated polymer poly (9,9-dioctyfluorene-co-benzothiazole) (F8BT) was used as the electron transporting layer (ETL) to modify cathode interface of inverted planar perovskite solar cell. Incorporation thin F8BT delivered greatly enhanced power conversion efficiency (PCE) 13.9% compared PCE 7.9% device without F8BT, due improvements in various performance parameters like V oc , J sc and FF . Moreover, great elimination hysteresis demonstrated based devices. These results suggest promising potential polymeric materials cells possible approach eliminate with this class interfacial materials.

参考文章(41)
Xueyan Wang, Xiaodong Li, Gang Tang, Lixiao Zhao, Wenjun Zhang, Tonggang Jiu, Junfeng Fang, Improving efficiency of planar hybrid CH3NH3PbI3-xClx perovskite solar cells by isopropanol solvent treatment Organic Electronics. ,vol. 24, pp. 205- 211 ,(2015) , 10.1016/J.ORGEL.2015.05.043
W. S. Yang, J. H. Noh, N. J. Jeon, Y. C. Kim, S. Ryu, J. Seo, S. I. Seok, High-performance photovoltaic perovskite layers fabricated through intramolecular exchange Science. ,vol. 348, pp. 1234- 1237 ,(2015) , 10.1126/SCIENCE.AAA9272
Lioz Etgar, Peng Gao, Zhaosheng Xue, Qin Peng, Aravind Kumar Chandiran, Bin Liu, Md. K. Nazeeruddin, Michael Grätzel, Mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells. Journal of the American Chemical Society. ,vol. 134, pp. 17396- 17399 ,(2012) , 10.1021/JA307789S
M. M. Lee, J. Teuscher, T. Miyasaka, T. N. Murakami, H. J. Snaith, Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Science. ,vol. 338, pp. 643- 647 ,(2012) , 10.1126/SCIENCE.1228604
Qifan Xue, Zhicheng Hu, Jiang Liu, Jiahui Lin, Chen Sun, Ziming Chen, Chunhui Duan, Jing Wang, Cheng Liao, Woon Ming Lau, Fei Huang, Hin-Lap Yip, Yong Cao, Highly efficient fullerene/perovskite planar heterojunction solar cells via cathode modification with an amino-functionalized polymer interlayer Journal of Materials Chemistry. ,vol. 2, pp. 19598- 19603 ,(2014) , 10.1039/C4TA05352D
Carrie L. Donley, Jana Zaumseil, Jens W. Andreasen, Martin M. Nielsen, Henning Sirringhaus, Richard H. Friend, Ji-Seon Kim, Effects of Packing Structure on the Optoelectronic and Charge Transport Properties in Poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) Journal of the American Chemical Society. ,vol. 127, pp. 12890- 12899 ,(2005) , 10.1021/JA051891J
Jun-Yuan Jeng, Yi-Fang Chiang, Mu-Huan Lee, Shin-Rung Peng, Tzung-Fang Guo, Peter Chen, Ten-Chin Wen, CH3NH3PbI3Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells Advanced Materials. ,vol. 25, pp. 3727- 3732 ,(2013) , 10.1002/ADMA.201301327
Y. He, S. Gong, R. Hattori, J. Kanicki, High performance organic polymer light-emitting heterostructure devices Applied Physics Letters. ,vol. 74, pp. 2265- 2267 ,(1999) , 10.1063/1.123862
Hardeep Singh Gill, Akshay Kokil, Lian Li, Ravi Mosurkal, Jayant Kumar, Solution processed flexible planar hybrid perovskite solar cells SPIE Organic Photonics + Electronics. ,vol. 9184, pp. 918418- ,(2014) , 10.1117/12.2061405
H. Zhou, Q. Chen, G. Li, S. Luo, T.-b. Song, H.-S. Duan, Z. Hong, J. You, Y. Liu, Y. Yang, Interface engineering of highly efficient perovskite solar cells Science. ,vol. 345, pp. 542- 546 ,(2014) , 10.1126/SCIENCE.1254050