The inductive effect: theory and quantitative assessment
作者： Otto Exner
DOI: 10.1002/(SICI)1099-1395(199904)12:4<265::AID-POC124>3.0.CO;2-O
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摘要: The concept of the inductive effect is defined in terms thermodynamics and its quantitative estimation reviewed. electrostatic (through-space) sigma-inductive (through-bond) theories are confronted experimental proofs evaluated, with result that both very approximate neither principle correct. isolated molecules (acids, bases, anions, cations) estimated separately by means isodesmic reactions. Copyright © 1999 John Wiley & Sons, Ltd.
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