Thermodynamics of crystallizing oligomer and polymer multi‐component systems

摘要: Crystallization seggregation of chain ends and chains is always observed in oligomer multi-component systems. The driving forces these processes can be classified by use the thermodynamics eutectoid If folded-chain crystallization does not appear, a defined relationship between length-and crystal thickness distributions predicted with its typical influence on melting transition. With local equilibrium there opportunity for quantitative description transition copolymers ethylene means same as used oligormers spite existing newtork. There only need taking into consideration varied solubility microphases. Swelling phenomena are treated quantitatively lines, thus, yielding length distribution crystallizable sequences pure copolymeres. The shown to depend swelling deformation non-crystallized regions which gives direct evidence existence molecular network. Hence, non-crystallizable units found principles present all systems involved, indicating general importance.