摘要: Improved versions of traditionally employed synthetic reactions and newly developed for thioamides thiolactams reported within five years are introduced in this chapter. As starting materials, carbonyl compounds such as aldehydes, ketones, acids, amides, esters used combination with elemental sulfur or other sources, amines. Alkynes, benzylic halides, amines, nitriles also provide the carbon atom C=S group. To achieve direct replacement oxygen ordinary amides atom, thionating reagents involving P=S bonds developed. Alternatively, reactive species generated situ.
springer.com
sci-hub.se 参考文章(90)
Arvind K. Yadav, Vishnu P. Srivastava, Lal Dhar S. Yadav, O,O-Diethyl dithiophosphoric acid mediated direct synthesis of thioamides from aldehydes and ketones Tetrahedron Letters. ,vol. 53, pp. 7113- 7116 ,(2012) , 10.1016/J.TETLET.2012.10.089
Mátyás Milen, Péter Ábrányi-Balogh, András Dancsó, György Keglevich, Microwave-assisted synthesis of thioamides with elemental sulfur Journal of Sulfur Chemistry. ,vol. 33, pp. 33- 41 ,(2012) , 10.1080/17415993.2011.640329
Helen Rachel Lagiakos, Ashley Walker, Marie-Isabel Aguilar, Patrick Perlmutter, Thionation of amides using a solid-supported P2S5 reagent under microwave irradiation Tetrahedron Letters. ,vol. 52, pp. 5131- 5132 ,(2011) , 10.1016/J.TETLET.2011.07.104
Daniel L. Priebbenow, Carsten Bolm, Recent advances in the Willgerodt–Kindler reaction Chemical Society Reviews. ,vol. 42, pp. 7870- 7880 ,(2013) , 10.1039/C3CS60154D
Bagher Eftekhari-Sis, Saleh Vahdati-Khajeh, S. Motahhareh Amini, Maryam Zirak, Mahnaz Saraei, Willgerodt–Kindler reaction of arylglyoxals with amines and sulfur in aqueous media: a simple and efficient synthesis of α-ketothioamides Journal of Sulfur Chemistry. ,vol. 34, pp. 464- 473 ,(2013) , 10.1080/17415993.2012.757614
Nidhin Paul, Ramalingam Sathishkumar, Chellathurai Anuba, Shanmugam Muthusubramanian, Reactions of diphenacylaniline and diphenacyl sulfide under Gewald conditions: generation of enamines and thioamides RSC Advances. ,vol. 3, pp. 7445- 7451 ,(2013) , 10.1039/C3RA21556C
José Ernesto Valdez-Rojas, Hulme Ríos-Guerra, Alma Leticia Ramírez-Sánchez, Guadalupe García-González, Cecilio Álvarez-Toledano, José Guadalupe López-Cortés, Rubén A Toscano, José Guillermo Penieres-Carrillo, None, A study of the Willgerodt–Kindler reaction to obtain thioamides and α-ketothioamides under solvent-less conditions Canadian Journal of Chemistry. ,vol. 90, pp. 567- 573 ,(2012) , 10.1139/V2012-030
Sadu Nageswara Rao, Darapaneni Chandra Mohan, Subbarayappa Adimurthy, H-β-zeolite catalyzed transamidation of carboxamides, phthalimide, formamides and thioamides with amines under neat conditions RSC Advances. ,vol. 5, pp. 95313- 95317 ,(2015) , 10.1039/C5RA16933J
Anna Wrona-Piotrowicz, Janusz Zakrzewski, Rémi Métivier, Arnaud Brosseau, Anna Makal, Krzysztof Woźniak, Efficient synthesis of pyrene-1-carbothioamides and carboxamides. Tunable solid-state fluorescence of pyrene-1-carboxamides RSC Advances. ,vol. 4, pp. 56003- 56012 ,(2014) , 10.1039/C4RA07045C
Tiago A. Fernandes, Hana Solařová, Ivana Císařová, Filip Uhlík, Martin Štícha, Petr Štěpnička, Synthesis of phosphinoferrocene amides and thioamides from carbamoyl chlorides and the structural chemistry of Group 11 metal complexes with these mixed-donor ligands. Dalton Transactions. ,vol. 44, pp. 3092- 3108 ,(2015) , 10.1039/C4DT03279A