Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4– (Q = S, Se) and (SnMe3)+
作者： M. S. Tarasenko , A. Yu. Ledneva , N. V. Kurat’eva , D. Yu. Naumov , Sung-Jin Kim
DOI: 10.1134/S1070328407120020
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摘要: The reactions of SnMe3Cl with salts the cluster anionic complexes [Re6Q8(CN)6]4− (Q = S, Se) gave novel [{(SnMe3)2(OH)}2{SnMe3}2{Re6S8(CN)6}] (I), (Me4N)2[{SnMe3(H2O)}2{Re6Se8(CN)6}] (II), [{(SnMe2)4(μ3-O)}2{Re6Se8(CN)6}] (III), and [(SnMe2)4(μ3-O)2(μ2-OH)2(H2O)2][{SnMe3 2{Re6Se8(CN)6}] (IV). structures I–IV were determined by X-ray diffraction. Compounds I, IV have chain CN-SnMe3-NC bridges between anions [Re6Q8(CN)6]4−. Compound II contains isolated fragments {SnMe3(H2O)}2{Re6Se8(CN)6}2−. In polymer framework compound III, [Re6Se8(CN)6]4− are bound complex cations [(SnMe2)4(μ3-O)2]4+ formed due to hydrolysis initial (SnMe3)Cl.
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