A novel series of asymmetric trinuclear M(III) complexes (M=Ti, V, Cr, Mn, Fe, Co) with the [M3O2]6+ core by a deoximation reaction exemplified by the V(III) complex

作者: Phalguni Chaudhuri , Martina Hess , Thomas Weyhermüller , Eckhard Bill , Hans-Jürgen Haupt

DOI: 10.1016/S1387-7003(97)00006-3

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摘要: Abstract Compounds with the general formula [Et3NH][MIII3(μ3-O)(Salox)2(HSalox)(Salmp)], where M(III)=Ti, V, Cr, Mn, Fe or Co, H2Salox=salicylaldoxime and H3Salmp=2-(bis(salicylideneamino)methyl)phenol, have been synthesized by a deoximation reaction of salicylaldoxime.

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