Transformation of aldehydes or alcohols to amides at room temperature under aqueous conditions
作者： Dao-Qing Dong , Shuang-Hong Hao , Hui Zhang , Zu-Li Wang
DOI: 10.1016/J.CCLET.2017.03.008
关键词:
摘要: Abstract A novel and efficient method for the synthesis of amide has been developed. The reactions proceeded smoothly under aqueous conditions at room temperature generated corresponding products in good to excellent yields. It is worth noting that alkyl amines which did not react known approaches are well tolerated our system.
elsevier.com
sci-hub.se 参考文章(23)
Bingnan Du, Bo Jin, Peipei Sun, The syntheses of α-ketoamides vianBu4NI-catalyzed multiple sp3C–H bond oxidation of ethylarenes and sequential coupling with dialkylformamides Organic and Biomolecular Chemistry. ,vol. 12, pp. 4586- 4589 ,(2014) , 10.1039/C4OB00520A
Subhash Chandra Ghosh, Joyce S. Y. Ngiam, Abdul M. Seayad, Dang Thanh Tuan, Christina L. L. Chai, Anqi Chen, Copper-catalyzed oxidative amidation of aldehydes with amine salts: synthesis of primary, secondary, and tertiary amides. Journal of Organic Chemistry. ,vol. 77, pp. 8007- 8015 ,(2012) , 10.1021/JO301252C
Hiroyuki Morimoto, Risa Fujiwara, Yuhei Shimizu, Kazuhiro Morisaki, Takashi Ohshima, Lanthanum(III) triflate catalyzed direct amidation of esters. Organic Letters. ,vol. 16, pp. 2018- 2021 ,(2014) , 10.1021/OL500593V
Seung Hwan Cho, Eun Jeong Yoo, Imhyuck Bae, Sukbok Chang, Copper-catalyzed hydrative amide synthesis with terminal alkyne, sulfonyl azide, and water. Journal of the American Chemical Society. ,vol. 127, pp. 16046- 16047 ,(2005) , 10.1021/JA056399E
John M. Humphrey, A. Richard Chamberlin, Chemical Synthesis of Natural Product Peptides: Coupling Methods for the Incorporation of Noncoded Amino Acids into Peptides. Chemical Reviews. ,vol. 97, pp. 2243- 2266 ,(1997) , 10.1021/CR950005S
Kekeli Ekoue-Kovi, Christian Wolf, One‐Pot Oxidative Esterification and Amidation of Aldehydes Chemistry: A European Journal. ,vol. 14, pp. 6302- 6315 ,(2008) , 10.1002/CHEM.200800353
Boopathy Gnanaprakasam, David Milstein, Synthesis of Amides from Esters and Amines with Liberation of H2 under Neutral Conditions Journal of the American Chemical Society. ,vol. 133, pp. 1682- 1685 ,(2011) , 10.1021/JA109944N
Xiaoying Liu, Klavs F. Jensen, Multistep synthesis of amides from alcohols and amines in continuous flow microreactor systems using oxygen and urea hydrogen peroxide as oxidants Green Chemistry. ,vol. 15, pp. 1538- 1541 ,(2013) , 10.1039/C3GC40407B
Gai-Li Li, Karen Ka-Yan Kung, Man-Kin Wong, Gold-catalyzed amide synthesis from aldehydes and amines in aqueous medium Chemical Communications. ,vol. 48, pp. 4112- 4114 ,(2012) , 10.1039/C2CC17689K
Bo Shen, Dawn M. Makley, Jeffrey N. Johnston, Umpolung reactivity in amide and peptide synthesis Nature. ,vol. 465, pp. 1027- 1032 ,(2010) , 10.1038/NATURE09125