Intercalation of Ferrocene and (Ferrocenylalkyl)ammonium Halides into the Gel-V2O5 Interlayer Space
作者： Shoji Okuno , Gen-etsu Matsubayashi
DOI: 10.1246/BCSJ.66.459
关键词:
摘要: Ferrocene, FcH, 1,1′-dimethylferrocene, FcMe2, some (ferrocenylalkyl)ammonium iodides, Fc(CH2)nNR2R′+I−, chlorides, Fc(CH2)nNR2R′+Cl− [Fc = (C5H5)Fe(C5H4); n 1 and 2; R, R′ H Me], benzyldimethyl-, benzyltrimethylammonium octylammonium iodides reacted with powdered gel-V2O5 suspended in ethanol to afford intercalation compounds; V2O5·(H2O)0.6·[Fc+H]0.27, V2O5·(H2O)0.6·[Fc+Me2]0.22, V2O5·(H2O)0.6·[Fc+CH2NHMe2+]0.16, V2O5·(H2O)0.6·[Fc+CH2NMe3+]0.15, V2O5·(H2O)0.8·[Fc+CH2CH2NH3+]0.21, V2O5·(H2O)0.8·[Fc+CH2CH2NMe3+]0.14, V2O5·(H2O)0.6·[Fc+CH2NHMe2+]0.18, V2O5·(H2O)0.6·[Fc+CH2CH2NH3+]0.22, V2O5·(H2O)0.6·[PhCH2NHMe2+]0.29, V2O5·(H2O)0.6·[PhCH2NMe3+]0.24, V2O5·(H2O)0.6·[n-C8H17NH3+]0.33. The compounds are constructed layered V2O5 moieties both V(IV) V(V) states the ferrocenium, ferrocenium derivatives, or cation interlayer space, producing single V2O5-interlayer spacings. Molecular arran...
csj.jp参考文章(25)
Byron Jordan, Crispin Calvo, Crystal Structure of α-VPO5 Canadian Journal of Chemistry. ,vol. 51, pp. 2621- 2625 ,(1973) , 10.1139/V73-396
R. Gopal, C. Calvo, Crystal structure of βVPO5 Journal of Solid State Chemistry. ,vol. 5, pp. 432- 435 ,(1972) , 10.1016/0022-4596(72)90089-8
N. Baffier, L. Znaidi, M. Huber, Synthesis of vanadium bronzes MxV2O5 through sol-gel processes II - orthorhombic bronzes (M = Ba2+, Ni2+, Al3+, Fe3+) Materials Research Bulletin. ,vol. 25, pp. 705- 713 ,(1990) , 10.1016/0025-5408(90)90198-B
J. Lemerle, L. Nejem, J. Lefebvre, Condensation process in polyvanadic acid solutions Journal of Inorganic and Nuclear Chemistry. ,vol. 42, pp. 17- 20 ,(1980) , 10.1016/0022-1902(80)80036-4
Kazuki Akiba, Gen-Etsu Matsubayashi, Toshio Tanaka, Spectroscopic and electrical properties of oxidized tris(dmit)vanadium anion complexes (dmit = 4,5-dimercapto-1,3-dithiole-2-thionate) Inorganica Chimica Acta. ,vol. 165, pp. 245- 248 ,(1989) , 10.1016/S0020-1693(00)83246-6
A. Bouhaouss, P. Aldebert, Intercalation d'ions alkylammonium et d'alkylamines a longues chaines dans les gels de V2O5 Materials Research Bulletin. ,vol. 18, pp. 1247- 1256 ,(1983) , 10.1016/0025-5408(83)90028-4
Shoji Okuno, Gen-etsu Matsubayashi, Intercalation of ferrocenylalkylammonium cations into the layered lattice of VOPO4 Journal of The Chemical Society-dalton Transactions. pp. 2441- 2444 ,(1992) , 10.1039/DT9920002441
Wen-hai Yu, Da-zhi Wang, Bin Zhu, Gui-en Zhou, Intercalation of Mg in V2O5 Solid State Communications. ,vol. 63, pp. 1043- 1044 ,(1987) , 10.1016/0038-1098(87)90657-0
Gerhard Ladwig, Über die Konstitution des VPO5(·nH2O) Zeitschrift für anorganische und allgemeine Chemie. ,vol. 338, pp. 266- 278 ,(1965) , 10.1002/ZAAC.19653380506
G. K. Wertheim, A. Rosencwaig, Characterization of Inequivalent Iron Sites in Prussian Blue by Photoelectron Spectroscopy The Journal of Chemical Physics. ,vol. 54, pp. 3235- 3237 ,(1971) , 10.1063/1.1675321