Radiation preparation of graphene/carbon nanotubes hybrid fillers for mechanical reinforcement of poly(vinyl alcohol) films

作者: Hui-Ling Ma , Long Zhang , Youwei Zhang , Shuojue Wang , Chao Sun

DOI: 10.1016/J.RADPHYSCHEM.2015.03.028

关键词:

摘要: Abstract Graphene/carbon nanotubes (G/CNTs) hybrid fillers were synthesized by γ -ray radiation reduction of graphene oxide (GO) in presence CNTs. The obtained with three-dimensional (3D) interconnected network structure characterized X-ray diffraction (XRD) and scanning electron microscope (SEM). Poly(vinyl alcohol) (PVA) composite films enhanced mechanical properties thermal stability subsequently prepared solution blending G/CNTs PVA matrix. tensile strength Young's modulus containing 1 wt% measured to be 81.9 MPa 3.9 GPa respectively, which 56% 33.6% higher than those pure PVA. These substantial improvements could attributed the 3D G/CNTs, homogeneous dispersion as well strong hydrogen-bonding interaction between macromolecular chains.

参考文章(26)
Yongseon Hwang, Myeongjin Kim, Jooheon Kim, Enhancement of thermal and mechanical properties of flexible graphene oxide/carbon nanotube hybrid films though direct covalent bonding Journal of Materials Science. ,vol. 48, pp. 7011- 7021 ,(2013) , 10.1007/S10853-013-7510-7
Xiaoming Yang, Liang Li, Songmin Shang, Xiao-ming Tao, None, Synthesis and characterization of layer-aligned poly(vinyl alcohol)/graphene nanocomposites Polymer. ,vol. 51, pp. 3431- 3435 ,(2010) , 10.1016/J.POLYMER.2010.05.034
Minqiang Sun, Gengchao Wang, Xingwei Li, Chunzhong Li, Irradiation preparation of reduced graphene oxide/carbon nanotube composites for high-performance supercapacitors Journal of Power Sources. ,vol. 245, pp. 436- 444 ,(2014) , 10.1016/J.JPOWSOUR.2013.06.145
Yazhou Zhou, Juan Yang, Xiaonong Cheng, Nan Zhao, Lei Sun, Hongbo Sun, Dan Li, Electrostatic self-assembly of graphene–silver multilayer films and their transmittance and electronic conductivity Carbon. ,vol. 50, pp. 4343- 4350 ,(2012) , 10.1016/J.CARBON.2012.04.069
Dingshan Yu, Liming Dai, Self-Assembled Graphene/Carbon Nanotube Hybrid Films for Supercapacitors The Journal of Physical Chemistry Letters. ,vol. 1, pp. 467- 470 ,(2010) , 10.1021/JZ9003137
Zuo-Jia Wang, Dong-Jun Kwon, Ga-Young Gu, Hak-Soo Kim, Dae-Sik Kim, Choon-Soo Lee, K. Lawrence DeVries, Joung-Man Park, Mechanical and interfacial evaluation of CNT/polypropylene composites and monitoring of damage using electrical resistance measurements Composites Science and Technology. ,vol. 81, pp. 69- 75 ,(2013) , 10.1016/J.COMPSCITECH.2013.04.001
Shin-Yi Yang, Kuo-Hsin Chang, Yuan-Li Huang, Ying-Feng Lee, Hsi-Wen Tien, Shin-Ming Li, Ying-Hui Lee, Chia-Hong Liu, Chen-Chi M Ma, Chi-Chang Hu, None, A powerful approach to fabricate nitrogen-doped graphene sheets with high specific surface area Electrochemistry Communications. ,vol. 14, pp. 39- 42 ,(2012) , 10.1016/J.ELECOM.2011.10.028
Jihao Li, Bowu Zhang, Linfan Li, Hongjuan Ma, Ming Yu, Jingye Li, γ-ray irradiation effects on graphene oxide in an ethylenediamine aqueous solution Radiation Physics and Chemistry. ,vol. 94, pp. 80- 83 ,(2014) , 10.1016/J.RADPHYSCHEM.2013.06.029
Long-Cheng Tang, Yan-Jun Wan, Dong Yan, Yong-Bing Pei, Li Zhao, Yi-Bao Li, Lian-Bin Wu, Jian-Xiong Jiang, Guo-Qiao Lai, The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites Carbon. ,vol. 60, pp. 16- 27 ,(2013) , 10.1016/J.CARBON.2013.03.050