On the structure of Pd, Pt and Rh complexes with 1,5-hexadiene
作者： I.A. Zakharova , L. Leites , V.T. Aleksanyan
DOI: 10.1016/S0022-328X(00)81502-8
关键词:
摘要: A number of halogen complexes Pd, Pt and Rh with 1,5-hexadiene have been synthesized;three them, C6H10PdBr2, C6H10PtBr2 (C6H10RhCl)2, for the first time. An intermediate while preparing C6H10PdCl2 was polynuclear polymeric moiety [C6H10(PdCl2)4]n· IR, Raman ESCA spectroscopy show that diallylic ligand in all has cis-configuration strength metaldiallyl bond increases series Pd < Rh.
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