Multifunctional Block Copolymer: Where Polymetallic and Polyelectrolyte Blocks Meet
作者： Mahboubeh Hadadpour , Jessica Gwyther , Ian Manners , Paul J. Ragogna
DOI: 10.1021/ACS.CHEMMATER.5B00752
关键词:
摘要: Sequential reversible addition–fragmentation transfer (RAFT) polymerization of a mixed sandwich cobaltocene monomer (η5-cyclopentadienyl-cobalt-η4-cyclobutadiene (CpCoCb)) and phosphonium salt functionalized styrene resulted in the first example unique multifunctional block copolymer consisting metallopolymer polyelectrolyte block. The was decorated with gold anion (AuCl4–) via metathesis, resulting heterobimetallic distinct cobalt sections. Solution self-assembly behavior this metallopolymer-b-polyelectrolyte before after metathesis studied. Heterobimetallic micelles containing core cobalt-containing corona were obtained, then reduced to form nanoparticles (AuNPs). Studies on solid-state showed that it phase separated into hexagonally packed cylinders. Salt phase-separated...
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sci-hub.se 参考文章(82)
Roger J. Mortimer, Aubrey L. Dyer, John R. Reynolds, Electrochromic organic and polymeric materials for display applications Displays. ,vol. 27, pp. 2- 18 ,(2006) , 10.1016/J.DISPLA.2005.03.003
Megan E.A. Fegley, Sherryllene S. Pinnock, Catherine N. Malele, Wayne E. Jones, Metal-containing conjugated polymers as fluorescent chemosensors in the detection of toxicants Inorganica Chimica Acta. ,vol. 381, pp. 78- 84 ,(2012) , 10.1016/J.ICA.2011.11.040
Cátia Crispilho Corrêa, Sergio Augusto Venturinelli Jannuzzi, Murilo Santhiago, Ronaldo Adriano Timm, André Luiz Barboza Formiga, Lauro Tatsuo Kubota, Modified electrode using multi-walled carbon nanotubes and a metallopolymer for amperometric detection of l-cysteine web science. ,vol. 113, pp. 332- 339 ,(2013) , 10.1016/J.ELECTACTA.2013.09.050
Hua Ren, Jianzhong Sun, Binjie Wu, Qiyun Zhou, Synthesis and properties of a phosphorus-containing flame retardant epoxy resin based on bis-phenoxy (3-hydroxy) phenyl phosphine oxide Polymer Degradation and Stability. ,vol. 92, pp. 956- 961 ,(2007) , 10.1016/J.POLYMDEGRADSTAB.2007.03.006
N. A. Yashtulov, A. N. Bol’shakova, A. A. Revina, V. R. Flid, Metallopolymer nanocomposites based on platinum nanoparticles for chemical fuel cells Russian Chemical Bulletin. ,vol. 60, pp. 1581- 1585 ,(2011) , 10.1007/S11172-011-0235-3
Tsutomu Mizuta, Yuki Imamura, Katsuhiko Miyoshi, Ring-Opening Reaction of Phosphorus-Bridged [1]Ferrocenophane via Ring Slippage from η5- to η1-Cp Journal of the American Chemical Society. ,vol. 125, pp. 2068- 2069 ,(2003) , 10.1021/JA029297M
Alan J. Lough, Ian Manners, Charles H. Honeyman, Daniel A. Foucher, Francisco Y. Dahmen, Rudy Rulkens, Thermal Ring-Opening Polymerization (ROP) of Strained, Ring-Tilted Phosphorus-Bridged [1]Ferrocenophanes: Synthesis of Poly(ferrocenylphosphines) and Poly(ferrocenylphosphine sulfides) Organometallics. ,vol. 14, pp. 5503- 5512 ,(1995) , 10.1021/OM00012A017
Chil-Won Lee, Ohyoung Kim, Myoung-Seon Gong, Humidity‐sensitive properties of new polyelectrolytes based on the copolymers containing phosphonium salt and phosphine function Journal of Applied Polymer Science. ,vol. 89, pp. 1062- 1070 ,(2003) , 10.1002/APP.12253
Chil-Won Lee, Myoung-Seon Gong, None, Resistive humidity sensor using phosphonium salt-containing polyelectrolytes based on the mutually cross-linkable copolymers Macromolecular Research. ,vol. 11, pp. 322- 327 ,(2003) , 10.1007/BF03218371
Y. Hammam, H. M. El-Ghanem, I. M. Arafa, M.R. Said, Ibrahim Abo-Aljarayesh, Magnetic behavior of polycarbosilazane FeII, FeIII and mixed-valence FeII–III chloride metallopolymers Polymer International. ,vol. 56, pp. 376- 380 ,(2007) , 10.1002/PI.2157