Gallium, Indium, and Thallium, Excluding Transition Metal Derivatives

作者: S. Schulz

DOI: 10.1016/B0-08-045047-4/00048-0

关键词:

摘要: This chapter deals with the synthesis of organometallic compounds group 13 elements Ga, In, and Tl, which contain at least one metal–carbon or metal–hydrogen bond. An overview about general synthetic pathways is given their structures reactivity are discussed. The current not only reviews organometallics in typical oxidation state III but also emphasizes on low-valent complexes, were almost unknown 10 years ago. In addition, heteroatomic groups 15 16

参考文章(656)
O. T. Beachley,, James R. Gardinier, Melvyn Rowen Churchill, Gallium(II) Compounds Stabilized by β-Diketonate Ligands: Synthesis, Characterization, and X-ray Structural Studies of [GaCl(acac)]2 and [GaCl(tmhd)]2 Organometallics. ,vol. 19, pp. 4544- 4549 ,(2000) , 10.1021/OM0000764
A. Kuczkowski, S. Fahrenholz, S. Schulz, M. Nieger, Reactions of Distibines Sb2R4 and Dibismuthine Bi2Et4 with Trialkyltrieles MR3 Organometallics. ,vol. 23, pp. 3615- 3621 ,(2004) , 10.1021/OM049746M
Marcus L. Cole, David E. Hibbs, Cameron Jones, Neil A. Smithies, Phosphine and phosphido indium hydride complexes and their use in inorganic synthesis Journal of The Chemical Society-dalton Transactions. pp. 545- 550 ,(2000) , 10.1039/A908418E
Frank J. Feher, Kamyar Rahimian, Theodore A. Budzichowski, Joseph W. Ziller, Thallium-Stabilized Silsesquioxides: Versatile Reagents for the Synthesis of Metallasilsesquioxanes, Including High-Valent Molybdenum-Containing Silsesquioxanes Organometallics. ,vol. 14, pp. 3920- 3926 ,(1995) , 10.1021/OM00008A043
C Jeff Harlan, Edward G Gillan, Simon G Bott, Andrew R Barron, None, TERT-AMYL COMPOUNDS OF ALUMINUM AND GALLIUM : HALIDES, HYDROXIDES, AND CHALCOGENIDES Organometallics. ,vol. 15, pp. 5479- 5488 ,(1996) , 10.1021/OM9605185
Gerald Linti, Ronald Frey, Kurt Polborn, Zur Chemie des Galliums. IV: Darstellung und Strukturen monomerer (2,2,6,6-Tetramethylpiperidino)gallane Chemische Berichte. ,vol. 127, pp. 1387- 1393 ,(1994) , 10.1002/CBER.19941270810
O. T. Beachley, John C. Pazik, Matthew J. Noble, Low Oxidation State Gallium Compounds. Synthesis and Characterization of Ga(CH2CMe3)n Organometallics. ,vol. 13, pp. 2885- 2889 ,(1994) , 10.1021/OM00019A051
Harold S Isom, Alan H Cowley, Andreas Decken, Frankwin Sissingh, Siegfried Corbelin, Richard J Lagow, None, Group 13 halides and hydrides with o-(aminomethyl)phenyl substituents Organometallics. ,vol. 14, pp. 2400- 2406 ,(1995) , 10.1021/OM00005A042