Model studies of force-dependent kinetics of multi-barrier reactions
作者： Yancong Tian , Timothy J. Kucharski , Qing-Zheng Yang , Roman Boulatov
DOI: 10.1038/NCOMMS3538
关键词:
摘要: In chemical reactions, inner barriers, which precede the rate-determining transition state, are kinetically invisible but mechanistically significant. On an example of reduction macrocyclic disulphides, authors quantify these barriers by studying reaction rate as a function applied force.
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