A Dynamic Organic Structuring-Directing Agent for Pure-Silica-Zeolite AST and LTA Syntheses
作者： Minwei SUN , Heather K. HUNT , Christopher M. LEW , Rui CAI , Yan LIU
DOI: 10.1016/S1872-2067(10)60291-4
关键词:
摘要: Pure-silica-zeolite (PSZ) AST and LTA are synthesized successfully by using the same structure-directing agent (SDA) molecule, but at different concentrations. A dynamic organic SDA is proposed to discuss mechanism of phase discrimination between LTA. Data suggest that molecules can self-assemble into dimer or trimer complexes concentrations π-π interactions, these differences be taken advantage selectively synthesize either PSZ These deviations from Liebau's rules indicate small changes in chemistry, structure, order solution have a great impact on structure selectivity zeolite synthesis.
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