1D Mn(III) coordination polymers exhibiting chiral symmetry breaking and weak ferromagnetism.
作者： Masaaki Nakamura , Shinya Hayami , Yang Kim , Jack Harrowfield , Sotaro Kusumoto
DOI: 10.1039/D1DT00569C
关键词:
摘要: Mn(III) complexes with achiral ligands, (E)-N-(2-((2-aminobenzylidene)amino)-2-methylpropyl)-5-X-2-hydroxybenzamide (HLX, X = H, Cl, Br, and I), crystallise as chiral conglomerates containing amide oxygen-bridged one-dimensional coordination polymers that exhibit weak ferromagnetism. The bulk products symmetry breaking in they do not contain equal amounts of enantiomers, though which is the dominant species depends on substituent X.
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ibt.lt参考文章(32)
R. D. Gillard, The Cotton Effect in Coordination Compounds Progress in Inorganic Chemistry. pp. 215- 276 ,(2007) , 10.1002/9780470166086.CH4
Ivan Bernal, Jiwen Cai, Salah S. Massoud, Steven F. Watkins, Frank R. Fronczek, THE PHENOMENON OF KRYPTORACEMIC CRYSTALLIZATION. PART 1. COUNTERION CONTROL OF CRYSTALLIZATION PATHWAY SELECTION. PART 4. THE CRYSTALLIZATION BEHAVIOR OF (+/−)-[Co(tren)(NO2)2]Br(I), (+/−)-[Co(tren)(NO2)2]2Br(ClO4) · H2O(II), (+/(−)-[Co(tren)(NO2)2]ClO4(III) AND ATTEMPTS TO SOLVE THE STRUCTURE OF (+/−)-[Co(tren)(NO2)2]NO3(IV) Journal of Coordination Chemistry. ,vol. 38, pp. 165- 181 ,(1996) , 10.1080/00958979608022702
Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim, A homochiral metal-organic porous material for enantioselective separation and catalysis Nature. ,vol. 404, pp. 982- 986 ,(2000) , 10.1038/35010088
Cristobal Viedma, Chiral Symmetry Breaking During Crystallization: Complete Chiral Purity Induced by Nonlinear Autocatalysis and Recycling Physical Review Letters. ,vol. 94, pp. 065504- ,(2005) , 10.1103/PHYSREVLETT.94.065504
Ivan Bernal, Roger A. Lalancette, A crystalline paradise – three substances exhibiting the following crystallization modes: (1) conglomerate, kryptoracemic and unbalanced (2) conglomerate and kryptoracemic Comptes Rendus Chimie. ,vol. 18, pp. 929- 934 ,(2015) , 10.1016/J.CRCI.2015.06.005
A. Szabo-Nagy, L. Keszthelyi, Demonstration of the parity-violating energy difference between enantiomers Proceedings of the National Academy of Sciences of the United States of America. ,vol. 96, pp. 4252- 4255 ,(1999) , 10.1073/PNAS.96.8.4252
Cristobal Viedma, Selective Chiral Symmetry Breaking during Crystallization: Parity Violation or Cryptochiral Environment in Control? Crystal Growth & Design. ,vol. 7, pp. 553- 556 ,(2007) , 10.1021/CG060698D
Jung Hee Yoon, Dae Won Ryu, Hyoung Chan Kim, Sung Won Yoon, Byoung Jin Suh, Chang Seop Hong, An End‐On Azide‐Bridged Antiferromagnetic Single‐Chain Magnet Involving Spin Canting and Field‐Induced Two‐Step Magnetic Transitions Chemistry: A European Journal. ,vol. 15, pp. 3661- 3665 ,(2009) , 10.1002/CHEM.200900250
D. F. EATON, Nonlinear optical materials. Science. ,vol. 253, pp. 281- 287 ,(1991) , 10.1126/SCIENCE.253.5017.281
R. M. Hazen, T. R. Filley, G. A. Goodfriend, Selective adsorption of L- and D-amino acids on calcite: Implications for biochemical homochirality Proceedings of the National Academy of Sciences of the United States of America. ,vol. 98, pp. 5487- 5490 ,(2001) , 10.1073/PNAS.101085998