Chemically Authentic Surrogate Mixture Model for the Thermophysical Properties of a Coal-Derived Liquid Fuel

作者: M. L. Huber , E. W. Lemmon , V. Diky , B. L. Smith , T. J. Bruno

DOI: 10.1021/EF800314B

关键词:

摘要: We developed a surrogate mixture model to represent the physical properties of coal-derived liquid fuel using only information obtained from gas chromatography−mass spectrometry analysis and recently “advanced distillation curve”. then predicted density, speed sound, viscosity compared them limited experimental data. The contains five components (n-propylcyclohexane, trans-decalin, α-methyldecalin, bicyclohexane, n-hexadecane), yet comparisons data demonstrate that is able sound speed, within 1, 4, 5%, respectively.

参考文章(79)
James F. Ely, H. J. M. Hanley, Prediction of transport properties. 1. Viscosity of fluids and mixtures Industrial & Engineering Chemistry Fundamentals. ,vol. 20, pp. 323- 332 ,(1981) , 10.1021/I100004A004
Delanie Lamprecht, Fischer-Tropsch Fuel for Use by the U.S. Military as Battlefield-Use Fuel of the Future Energy & Fuels. ,vol. 21, pp. 1448- 1453 ,(2007) , 10.1021/EF060607M
Nikos G. Tsierkezos, Ioanna E. Molinou, George A. Polizos, Relative permittivities, speeds of sound, viscosities, and densities of cyclohexanone + cis-decalin and cyclohexanone + trans-decalin mixtures at 283.15, 293.15, and 303.15 K Journal of Chemical & Engineering Data. ,vol. 47, pp. 1492- 1495 ,(2002) , 10.1021/JE020084M
Kazuyuki Ohnishi, Ichiro Fujihara, Sachio Murakami, Thermodynamic properties of decalins mixed with hexane isomers at 298.15 K. II. Excess volumes and isentropic compressibilities Fluid Phase Equilibria. ,vol. 46, pp. 73- 84 ,(1989) , 10.1016/0378-3812(89)80276-6
B. J. Gudzinowicz, R. H. Campbell, J. S. Adams, Specific Heat Measurements of Complex Saturated Hydrocarbons. Journal of Chemical & Engineering Data. ,vol. 8, pp. 201- 204 ,(1963) , 10.1021/JE60017A018
Mikhail F. Bolotnikov, Yurij A. Neruchev, Yurij F. Melikhov, Vyacheslav N. Verveyko, Marina V. Verveyko, Temperature Dependence of the Speed of Sound, Densities, and Isentropic Compressibilities of Hexane + Hexadecane in the Range of (293.15 to 373.15) K Journal of Chemical & Engineering Data. ,vol. 50, pp. 1095- 1098 ,(2005) , 10.1021/JE050060Q
David L. Morgan, Riki Kobayashi, Direct vapor pressure measurements of ten n-alkanes m the 10-C28 range Fluid Phase Equilibria. ,vol. 97, pp. 211- 242 ,(1994) , 10.1016/0378-3812(94)85017-8
G. Tardajos, M. Diaz Pena, A. Lainez, E. Aicart, Speed of sound in and isothermal compressibility and isobaric expansivity of pure liquids at 298.15 K Journal of Chemical & Engineering Data. ,vol. 31, pp. 492- 493 ,(1986) , 10.1021/JE00046A031