Influence of Citric Acid on the Properties of Glycerol-Plasticised Cornstarch Extrusion Blends:

作者: Wang Ning , Yu Jiugao , Han Chunmei

DOI: 10.1177/096739110701500704

关键词:

摘要: Melt extrusion was used to prepare glycerol-plasticised dry thermoplastic starch (DTPS) in a single-screw extruder. Glycerol combined with water-plasticised (TPS) studied as standard. Citric acid (CA) accelerate the plasticization of DTPS. Scanning electron microscopy revealed that residual granules existed DTPS and plasticisation could be enhanced by CA. Rheological studies proved CA decreases shear viscosity improves fluidity TPS It also Fourier transform infrared spectroscopy glycerol form strong hydrogen bonds presence With increasing content, rigid fragile materials became more flexible, high tensile strength. Dynamic mechanical thermal analysis decrease glass transition temperature increase interaction between starch. Finally, water absorption were measured.

参考文章(14)
Donald Garlotta, A Literature Review of Poly(Lactic Acid) Journal of Polymers and The Environment. ,vol. 9, pp. 63- 84 ,(2001) , 10.1023/A:1020200822435
A CARVALHO, M ZAMBON, A DASILVACURVELO, A GANDINI, Thermoplastic starch modification during melt processing: Hydrolysis catalyzed by carboxylic acids Carbohydrate Polymers. ,vol. 62, pp. 387- 390 ,(2005) , 10.1016/J.CARBPOL.2005.08.025
Jeroen J. G. van Soest, Pieter M. Kortleve, The influence of maltodextrins on the structure and properties of compression-molded starch plastic sheets Journal of Applied Polymer Science. ,vol. 74, pp. 2207- 2219 ,(1999) , 10.1002/(SICI)1097-4628(19991128)74:9<2207::AID-APP10>3.0.CO;2-3
Stephan H.D. Hulleman, Frank H.P. Janssen, Herman Feil, The role of water during plasticization of native starches Polymer. ,vol. 39, pp. 2043- 2048 ,(1998) , 10.1016/S0032-3861(97)00301-7
J.J.G. van Soest, K. Benes, D. de Wit, J.F.G. Vliegenthart, The influence of starch molecular mass on the properties of extruded thermoplastic starch Polymer. ,vol. 37, pp. 3543- 3552 ,(1996) , 10.1016/0032-3861(96)00165-6
Yu Jiugao, Wang Ning, Ma Xiaofei, The Effects of Citric Acid on the Properties of Thermoplastic Starch Plasticized by Glycerol Starch-starke. ,vol. 57, pp. 494- 504 ,(2005) , 10.1002/STAR.200500423
A Pawlak, M Mucha, Thermogravimetric and FTIR studies of chitosan blends Thermochimica Acta. ,vol. 396, pp. 153- 166 ,(2003) , 10.1016/S0040-6031(02)00523-3