Utilizing egg lecithin coating to improve the electrochemical performance of regenerated lithium iron phosphate

作者: Peipei Zhu , Zhenyu Yang , Hai Zhang , Ji Yu , Ze Zhang

DOI: 10.1016/J.JALLCOM.2018.02.119

关键词:

摘要: Abstract A series of egg lecithin coating LiFePO4 composites have been prepared by a simple mechanochemistry activation and sintering processes using the regenerated as raw materials. The mechanical forces high energy ball milling induced or chemical changes different components. as-prepared showed stable (C+N+P) co-coating layers with N-C P-C bonds wrapped particles smaller uniform particle sizes, which can shorten diffusion distance lithium ions electrons, offer good electronic conduction between particles. LiFePO4/C composite 15% exhibited average specific capacities 164.9 mAh g−1 at low C-rate 0.2 C; 5 C, electrode deliver capacity 120 mAh retention 93% after 100 cycles; even rate 20 C, this materials still keep 100.7 mAh g−1, is 41% greater than its pristine counterpart. More interestingly, material in work recycled produced from spent power batteries, also demonstrates greatly potential approach to utilize batteries into high-performance cathode for Li-ion applications.

参考文章(46)
Huiyuan Zheng, Li Tan, Li Zhang, Qunting Qu, Zhongming Wan, Yan Wang, Ming Shen, Honghe Zheng, Correlation between lithium deposition on graphite electrode and the capacity loss for LiFePO4/graphite cells Electrochimica Acta. ,vol. 173, pp. 323- 330 ,(2015) , 10.1016/J.ELECTACTA.2015.05.039
Ming Shi, Ling-Bin Kong, Jin-Bei Liu, Kun Yan, Jia-Jia Li, Yan-Hua Dai, Yong-Chun Luo, Long Kang, A novel carbon source coated on C-LiFePO4 as a cathode material for lithium-ion batteries Ionics. ,vol. 22, pp. 185- 192 ,(2016) , 10.1007/S11581-015-1549-1
Sheng Chen, Jingjing Duan, Mietek Jaroniec, Shi-Zhang Qiao, Nitrogen and Oxygen Dual-Doped Carbon Hydrogel Film as a Substrate-Free Electrode for Highly Efficient Oxygen Evolution Reaction Advanced Materials. ,vol. 26, pp. 2925- 2930 ,(2014) , 10.1002/ADMA.201305608
Cong Wang, Ziyang Guo, Wei Shen, Qunjie Xu, Haimei Liu, Yonggang Wang, B-doped Carbon Coating Improves the Electrochemical Performance of Electrode Materials for Li-ion Batteries Advanced Functional Materials. ,vol. 24, pp. 5511- 5521 ,(2014) , 10.1002/ADFM.201401006
Jiexin Dang, Feng Xiang, Ningyu Gu, Rongbin Zhang, Rahul Mukherjee, Il-Kwon Oh, Nikhil Koratkar, Zhenyu Yang, Synthesis and electrochemical performance characterization of Ce-doped Li 3 V 2 (PO 4 ) 3 /C as cathode materials for lithium-ion batteries Journal of Power Sources. ,vol. 243, pp. 33- 39 ,(2013) , 10.1016/J.JPOWSOUR.2013.05.113
Denisa Hulicova-Jurcakova, Alexander M Puziy, Olga I Poddubnaya, Fabian Suárez-García, Juan MD Tascón, Gao Qing Lu, None, Highly stable performance of supercapacitors from phosphorus-enriched carbons. Journal of the American Chemical Society. ,vol. 131, pp. 5026- 5027 ,(2009) , 10.1021/JA809265M
Jing Li, Li Zhang, Longfei Zhang, Weiwei Hao, Haibo Wang, Qunting Qu, Honghe Zheng, In-situ growth of graphene decorations for high-performance LiFePO4 cathode through solid-state reaction Journal of Power Sources. ,vol. 249, pp. 311- 319 ,(2014) , 10.1016/J.JPOWSOUR.2013.10.106
Li Tan, Li Zhang, Qingna Sun, Ming Shen, Qunting Qu, Honghe Zheng, Capacity loss induced by lithium deposition at graphite anode for LiFePO4/graphite cell cycling at different temperatures Electrochimica Acta. ,vol. 111, pp. 802- 808 ,(2013) , 10.1016/J.ELECTACTA.2013.08.074
Ping Chen, Tian-Yuan Xiao, Yu-Hong Qian, Shan-Shan Li, Shu-Hong Yu, A Nitrogen‐Doped Graphene/Carbon Nanotube Nanocomposite with Synergistically Enhanced Electrochemical Activity Advanced Materials. ,vol. 25, pp. 3192- 3196 ,(2013) , 10.1002/ADMA.201300515
Zhaoping Liu, Renzhi Ma, Minoru Osada, Nobuo Iyi, Yasuo Ebina, Kazunori Takada, Takayoshi Sasaki, Synthesis, anion exchange, and delamination of Co-Al layered double hydroxide: assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies. Journal of the American Chemical Society. ,vol. 128, pp. 4872- 4880 ,(2006) , 10.1021/JA0584471