New rhodium complexes anchored on modified USY zeolites. A remarkable effect of the support on the enantioselectivity of catalytic hydrogenation of prochiral alkenes
作者： A. Corma , M. Iglesias , C. del Pino , F. Sánchez
DOI: 10.1039/C39910001253
关键词:
摘要: Rh-complexes with N-based chiral ligands, when anchored on a modified USY-zeolite which contains profuse supermicropores, produce remarkable increase of enantioselectivity (>95%) in the hydrogenation N-acyldehydrophenylalanine derivatives and represent truly heterogeneous counterpart homogeneous organometallic catalysts.
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