Supramolecular control on chemo- and regioselectivity via encapsulation of (NHC)-Au catalyst within a hexameric self-assembled host.
作者： Alessandra Cavarzan , Alessandro Scarso , Paolo Sgarbossa , Giorgio Strukul , Joost N. H. Reek
DOI: 10.1021/JA111106X
关键词:
摘要: The encapsulation of a Au(I) catalyst within self-assembled, hydrogen bonded, hexameric capsule dramatically changes its catalytic activity, leading to unusual products due the steric requirements host’s cavity.
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Douglas B. Grotjahn, Daniel A. Lev, A General Bifunctional Catalyst for the Anti-Markovnikov Hydration of Terminal Alkynes to Aldehydes Gives Enzyme-Like Rate and Selectivity Enhancements Journal of the American Chemical Society. ,vol. 126, pp. 12232- 12233 ,(2004) , 10.1021/JA046360U