作者: R. D. Levine
DOI: 10.1007/978-94-011-0345-9_9
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摘要: The thesis that ‘chemical reactions proceed in the most statistical way, subject to constraints’ is discussed with examples drawn mainly from direct reactions. Attention centered on technical aspects and their motivation, special reference notions of ‘entropy’, ‘the prior distribution’ constraints. Surprisal analysis emphasized Lagrangian form, which particularly useful when several constraints are imposed, discussed. More advanced topics such as surprisal synthesis reviewed.