Synthesis, Properties, and Structures of Low‐Melting Tetraisocyanatocobaltate(II)‐Based Ionic Liquids
作者： Tim Peppel , Alexander Hinz , Philipp Thiele , Monika Geppert-Rybczyńska , Jochen K. Lehmann
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摘要: A series of new ionic liquids the formula Ax[CoII(NCO)4] with [CoII(NCO)4]2 anion and nitrogen-based organic cations was synthesized. The single crystal structures all compounds were determined by X-ray diffraction reveal for cases existence discrete ions. magnetic behavior at room temperature is paramagnetic resulting from high-spin tetrahedrally coordinated CoII Melting points or glass transition temperatures are found in range some singly charged cations, above 100 °C doubly [PPN]+ salt. Each compound has been characterized elemental analysis, NMR-, IR-, UV/Vis- spectroscopy. Measurements density, dynamic viscosity, conductivity surface tension low melting substance [EMIm]2[Co(NCO)4] show, that they differ slightly but generally comparable to corresponding values isothiocyanato complexes.
sci-hub.se 参考文章(87)
Itzia Irene Padilla-Martínez, Armando Ariza-Castolo, Rosalinda Contreras, NMR Study of isolobalN-CH3+,N-BH3 andN-BF3 imidazole derivatives Magnetic Resonance in Chemistry. ,vol. 31, pp. 189- 193 ,(1993) , 10.1002/MRC.1260310207
Guoying Zhao, Tao Jiang, Haixiang Gao, Buxing Han, Jun Huang, Donghai Sun, Mannich reaction using acidic ionic liquids as catalysts and solvents Green Chemistry. ,vol. 6, pp. 75- 77 ,(2004) , 10.1039/B309700P
G. Tammann, W. Hesse, Die Abhängigkeit der Viscosität von der Temperatur bie unterkühlten Flüssigkeiten Zeitschrift für anorganische und allgemeine Chemie. ,vol. 156, pp. 245- 257 ,(1926) , 10.1002/ZAAC.19261560121
Hai-Juan Du, Li-Wei Mi, Zhong-Cheng Yue, Yun-Yin Niu, Hong-Wei Hou, Templated fabrication, isomer recognition of series of 1,1′-(alkane-1,ω-diyl)-bis(3-methylimidazolium)-induced polyoxometalates (ω = 1–11) Inorganica Chimica Acta. ,vol. 409, pp. 418- 426 ,(2014) , 10.1016/J.ICA.2013.09.050
Sandip K Sur, Measurement of magnetic susceptibility and magnetic moment of paramagnetic molecules in solution by high-field Fourier transform NMR spectroscopy Journal of Magnetic Resonance. ,vol. 82, pp. 169- 173 ,(1989) , 10.1016/0022-2364(89)90178-9
Monika Geppert-Rybczyńska, Jochen K. Lehmann, Andreas Heintz, Physicochemical properties of two 1-alkyl-1-methylpyrrolidinium bis[(trifluoromethyl)sulfonyl]imide ionic liquids and of binary mixtures of 1-butyl-1-methylpyrrolidinium bis[(trifluoromethyl)sulfonyl]imide with methanol or acetonitrile The Journal of Chemical Thermodynamics. ,vol. 71, pp. 171- 181 ,(2014) , 10.1016/J.JCT.2013.12.009
S. Zein El Abedin, E.M. Moustafa, R. Hempelmann, H. Natter, F. Endres, Additive free electrodeposition of nanocrystalline aluminium in a water and air stable ionic liquid Electrochemistry Communications. ,vol. 7, pp. 1111- 1116 ,(2005) , 10.1016/J.ELECOM.2005.08.010
J.P. Fackler, G.E. Dolbear, D. Coucouvanis, A tetrahedral complex of nickel(II) with the pseudo-halide cyanate Journal of Inorganic and Nuclear Chemistry. ,vol. 26, pp. 2035- 2037 ,(1964) , 10.1016/0022-1902(64)80032-4
Helen L Ngo, Karen LeCompte, Liesl Hargens, Alan B McEwen, Thermal properties of imidazolium ionic liquids Thermochimica Acta. ,vol. 357, pp. 97- 102 ,(2000) , 10.1016/S0040-6031(00)00373-7
L. E. Orgel, Spectra of Transition‐Metal Complexes Journal of Chemical Physics. ,vol. 23, pp. 1004- 1014 ,(1955) , 10.1063/1.1742182