Development of low-pH cementitious materials for HLRW repositories: Resistance against ground waters aggression

作者: J.L. García Calvo , A. Hidalgo , C. Alonso , L. Fernández Luco

DOI: 10.1016/J.CEMCONRES.2009.11.008

关键词:

摘要: One of the most accepted engineering construction concepts underground repositories for high radioactive waste considers use low-pH cementitious materials. This paper deals with design those based on Ordinary Portland Cements contents silica fume and/or fly ashes that modify concrete 'standard' properties, pore fluid composition and microstructure hydrated products. Their resistance to long-term groundwater aggression is also evaluated. The results show OPC cement binders content produces waters these pastes different from conventional ones, generating C-S-H gels lower CaO/SiO{sub 2} ratios possibly bind alkali ions. Leaching tests a good concretes against although an altered front can be observed.

参考文章(30)
Sung-Yoon Hong, F.P Glasser, Alkali sorption by C-S-H and C-A-S-H gels: Part II. Role of alumina Cement and Concrete Research. ,vol. 32, pp. 1101- 1111 ,(2002) , 10.1016/S0008-8846(02)00753-6
Ivan Klur, Benoît Pollet, Joseph Virlet, André Nonat, C-S-H Structure Evolution with Calcium Content by Multinuclear NMR Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials. pp. 119- 141 ,(1998) , 10.1007/978-3-642-80432-8_8
M C Hicks, T A Durning, Using microsilica to increase concrete's resistance to aggressive chemicals Concrete international. ,vol. 13, pp. 42- 48 ,(1991)
L. Fernandez, C. Alonso, C. Andrade, A. Hidalgo, The interaction of magnesium in hydration of C3S and CSH formation using 29Si MAS-NMR Journal of Materials Science. ,vol. 43, pp. 5772- 5783 ,(2008) , 10.1007/S10853-008-2889-2
Sung-Yoon Hong, F.P. Glasser, Alkali binding in cement pastes Cement and Concrete Research. ,vol. 29, pp. 1893- 1903 ,(1999) , 10.1016/S0008-8846(99)00187-8
P. Lovera, P. Le Bescop, F. Adenot, G. Li, Y. Tanaka, E. Owaki, Physico-chemical transformations of sulphated compounds during the leaching of highly sulphated cemented wastes Cement and Concrete Research. ,vol. 27, pp. 1523- 1532 ,(1997) , 10.1016/S0008-8846(97)00165-8
P Faucon, F Adenot, J.F Jacquinot, J.C Petit, R Cabrillac, M Jorda, Long-term behaviour of cement pastes used for nuclear waste disposal: review of physico-chemical mechanisms of water degradation Cement and Concrete Research. ,vol. 28, pp. 847- 857 ,(1998) , 10.1016/S0008-8846(98)00053-2
Xiandong Cong, R.James Kirkpatrick, 29Si MAS NMR study of the structure of calcium silicate hydrate Advanced Cement Based Materials. ,vol. 3, pp. 144- 156 ,(1996) , 10.1016/S1065-7355(96)90046-2
D.R.M. Brew, F.P. Glasser, Synthesis and characterisation of magnesium silicate hydrate gels Cement and Concrete Research. ,vol. 35, pp. 85- 98 ,(2005) , 10.1016/J.CEMCONRES.2004.06.022