Photochemical studies of unimolecular processes. II. Isomerization and quenching of vibrationally excited cycloheptatriene
作者：
关键词:
摘要: Experimental data on the thermal isomerizations of cycloheptatriene (CHT) and CHT-d 8 to toluene are used calculate rate constants for these at different energies. Application photochemical studies reported in part I shows that quenching vibrationally excited CHT is a multistep process, average energies removed per collision (kJ/mol) being: CHT, 17 ± 5; toluene, 11 SF 6 , 5.9 0.9; CO 2 3.8 0.4; He, 0.6 0.1.
harvard.edu
royalsocietypublishing.org
sci-hub.se 参考文章(6)
R. E. Harrington, B. S. Rabinovitch, M. R. Hoare, Collisional Deactivation of Vibrationally Excited sec‐Butyl‐d1 Radicals Produced by Chemical Activation The Journal of Chemical Physics. ,vol. 33, pp. 744- 747 ,(1960) , 10.1063/1.1731251
P.C. Haarhoff, Semi-classical approximation to density of vibrational energy levels Molecular Physics. ,vol. 6, pp. 337- 339 ,(1963) , 10.1080/00268976300100381
M. V. Evans, R. C. Lord, Vibrational Spectra and Structure of the Tropilidene Molecule1 Journal of the American Chemical Society. ,vol. 82, pp. 1876- 1882 ,(1960) , 10.1021/JA01493A011
Gerald B. Porter, B. T. Connelly, Kinetics of Excited Molecules. II. Dissociation Processes The Journal of Chemical Physics. ,vol. 33, pp. 81- 85 ,(1960) , 10.1063/1.1731139
The primary process in the photolysis of hexafluoroacetone vapour V. Mechanistic considerations Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 306, pp. 541- 551 ,(1968) , 10.1098/RSPA.1968.0168
Samuel Glasstone, The theory of rate processes ,(1941)