2-Amino 4-methylpyridinium 3-chlorobenzoate - A phase matchable organic nonlinear optical material for optoelectronics device applications
作者： B. Babu , J. Chandrasekaran , R. Thirumurugan , K. Anitha , M. Saravanabhavan
DOI: 10.1016/J.OPTLASTEC.2017.04.007
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摘要: Abstract 2-Amino 4-methylpyridinium 3-chlorobenzoate (2A4M3CB) was synthesized and good quality single crystals of the size 8 × 2 × 1.2 mm3 were harvested from methanol by slow evaporation solution growth technique at ambient temperature. Single crystal XRD reveals that 2A4M3CB crystallized in monoclinic system with noncentrosymmetric space group P21. The crystalline phases functional groups have been identified confirmed through powder X-ray diffraction Fourier transform infrared (FTIR) studies, respectively. 1H 13C NMR recorded to interpret molecular structure. optical transmittance window lower cutoff wavelength UV–Vis–NIR studies. Thermal mechanical stability explained TG/DTA Vickers hardness analysis. Charge transport mechanism photo response properties analyzed dielectric photoconductivity Powder second harmonic generation (SHG) characteristics phase matching ability explored Kurtz Perry SHG technique.
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sci-hub.se 参考文章(40)
P. Nagapandiselvi, C. Baby, R. Gopalakrishnan, Synthesis, growth, structure and nonlinear optical properties of a semiorganic 2-carboxy pyridinium dihydrogen phosphate single crystal Optical Materials. ,vol. 47, pp. 398- 405 ,(2015) , 10.1016/J.OPTMAT.2015.06.012
J. Mary Linet, S. Jerome Das, Optical, mechanical and transport properties of unidirectional grown l-tartaric acid bulk single crystal for non-linear optical application Materials Chemistry and Physics. ,vol. 126, pp. 886- 890 ,(2011) , 10.1016/J.MATCHEMPHYS.2010.12.020
L. Mariappan, A. Kandasamy, M. Rathnakumari, P. Sureshkumar, Synthesis, growth and properties of an organic nonlinear optical crystal: 2-Aminopyridinium benzoate (2-APB) Optik. ,vol. 124, pp. 2630- 2634 ,(2013) , 10.1016/J.IJLEO.2012.07.031
S. Senthil, S. Pari, P. Sagayaraj, J. Madhavan, Studies on the electrical, linear and nonlinear optical properties of Meta nitroaniline, an efficient NLO crystal Physica B-condensed Matter. ,vol. 404, pp. 1655- 1660 ,(2009) , 10.1016/J.PHYSB.2009.01.042
Seong-Ji Kwon, Mojca Jazbinsek, O-Pil Kwon, Peter Günter, Crystal Growth and Morphology Control of OH1 Organic Electrooptic Crystals Crystal Growth & Design. ,vol. 10, pp. 1552- 1558 ,(2010) , 10.1021/CG900882H
V. Kannan, K. Thirupugalmani, S. Brahadeeswaran, Studies on vibrational, NMR spectra and quantum chemical calculations of N-Succinopyridine: An organic nonlinear optical material Journal of Molecular Structure. ,vol. 1049, pp. 268- 279 ,(2013) , 10.1016/J.MOLSTRUC.2013.06.055
S. Brahadeeswaran, S. Onduka, M. Takagi, Y. Takahashi, H. Adachi, M. Yoshimura, Y. Mori, T. Sasaki, Growth of high-quality DAST crystals for THz applications Journal of Crystal Growth. ,vol. 292, pp. 441- 444 ,(2006) , 10.1016/J.JCRYSGRO.2006.04.052
G. S. Trivikrama Rao, S. K. Arora, N. M. Batra, Vickers micromechanical indentation of BaMoO4 crystals Journal of Materials Science. ,vol. 19, pp. 297- 302 ,(1984) , 10.1007/BF00553021
P. Srinivasan, T. Kanagasekaran, R. Gopalakrishnan, A Highly Efficient Organic Nonlinear Optical Donor−Acceptor Single Crystal: l-Valinium Picrate Crystal Growth & Design. ,vol. 8, pp. 2340- 2345 ,(2008) , 10.1021/CG701143N
M.R. Sridhar, M.M. Yovanovich, Empirical methods to predict Vickers microhardness Wear. ,vol. 193, pp. 91- 98 ,(1996) , 10.1016/0043-1648(95)06681-0