Rhodium(0) nanoparticles supported on ceria as catalysts in hydrogenation of neat benzene at room temperature.
作者： Serdar Akbayrak
DOI: 10.1016/J.JCIS.2018.07.011
关键词:
摘要: Abstract Rhodium(0) nanoparticles supported on ceria (Rh NPs/CeO2) were prepared from the reduction of Rh3+ ions surface in aqueous medium. Rh NPs/CeO2 catalyst was found to be highly active hydrogenation benzene under mild conditions. It provided a TOF value 495 h−1 solventless ∼3 bar pressure H2 gas at 25.0 ± 0.1 °C. shows superior catalytic activity over titania, zirconia and hafnia NPs this reaction.
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