Featured structures of fire residue of high‐impact polystyrene/organically modified montmorillonite nanocomposites during burning

作者: Jun Zhang , Maojuan Bai , Yong Wang , Fengyan Xiao

DOI: 10.1002/FAM.1128

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摘要: SUMMARY The structures and constituents of fire residue high-impact polystyrene/organically modified montmorillonite (HIPS/OMMT) nanocomposite during burning was investigated using scanning electron microscopy, thermogravimetric analysis, X-ray diffraction elementary analysis techniques based on quenched samples obtained the cone calorimeter test. It found that HIPS/OMMT tends to form a two-layer structure surface material. This contains thin condensed skin layer at top loose expanded cellular under layer. The many small sizes voids, while includes large number large-size voids. Both layers are composed mainly platelets, which aggregated nanoscale network structure, in certain amounts carbonaceous char components trapped but decompose above approximately 550°C presence oxygen. Finally, an idealized model put forward explain featured residues for studied. Copyright © 2012 John Wiley & Sons, Ltd.

参考文章(17)
Jeffrey W. Gilman, Flame Retardant Mechanism of Polymer–Clay Nanocomposites John Wiley & Sons, Ltd. pp. 67- 87 ,(2006) , 10.1002/9780470109038.CH3
Jeffrey W. Gilman, Richard H. Harris, John R. Shields, Takashi Kashiwagi, Alexander B. Morgan, A study of the flammability reduction mechanism of polystyrene-layered silicate nanocomposite: layered silicate reinforced carbonaceous char Polymers for Advanced Technologies. ,vol. 17, pp. 263- 271 ,(2006) , 10.1002/PAT.682
B. Schartel, M. Bartholmai, U. Knoll, Some comments on the main fire retardancy mechanisms in polymer nanocomposites Polymers for Advanced Technologies. ,vol. 17, pp. 772- 777 ,(2006) , 10.1002/PAT.792
M. Zanetti, T. Kashiwagi, L. Falqui, G. Camino, Cone Calorimeter Combustion and Gasification Studies of Polymer Layered Silicate Nanocomposites. Chemistry of Materials. ,vol. 14, pp. 881- 887 ,(2002) , 10.1021/CM011236K
Yu-Zhong Wang, 2010 Symposium on Flame-Retardant Materials & Technologies (ISFRMT2010), Chengdu, China, 2010 Polymers for Advanced Technologies. ,vol. 22, pp. 1083- 1084 ,(2011) , 10.1002/PAT.2007
Alberto Fina, Giovanni Camino, Ignition mechanisms in polymers and polymer nanocomposites Polymers for Advanced Technologies. ,vol. 22, pp. 1147- 1155 ,(2011) , 10.1002/PAT.1971
Jin Zhu, Charles A Wilkie, Thermal and Fire Studies on Polystyrene-Clay Nanocomposites Polymer International. ,vol. 49, pp. 1158- 1163 ,(2000) , 10.1002/1097-0126(200010)49:10<1158::AID-PI505>3.0.CO;2-G